The role of open-volume defects in the annihilation of antisites in a B2-ordered alloy
2019
Abstract The atomic arrangement in certain B2-ordered alloys, such as Fe 60 Al 40 , determines intrinsic material properties like magnetism. Here we have investigated the influence of open-volume defects on the atomic ordering process at elevated temperatures in Fe 60 Al 40 thin films. A dependence of the ordering process on the type and concentration of defects is observed by positron annihilation spectroscopy combined with ab-initio calculations. Comparing the lifetimes of positrons in the alloy for different annealing and irradiation treatments reveals the role of mono-vacancies, triple defects as well as large vacancy clusters: The rate of atomic ordering to the ordered B2 state is increased in the presence of mono-vacancies whereas triple defects and vacancy complexes decrease the ordering rate. Furthermore, an agglomeration of vacancies during annealing to di-vacancies and larger vacancy clusters is observed. The distribution of open-volume defects can be modified in such a way as to control the thermal stability via ion-irradiation and thermal pre-treatments.
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