Sulfation and lean/rich desulfation of a NOx storage reduction catalyst: Experimental and simulation study

A detailed study of the sulfation and desulfation phenomena of a NOx storage reduction catalyst using synthetic gas bench is presented. The experimental observations and results were put together, in order to develop a model, which can simulate the NOx storage reduction catalyst behavior during the sulfation and desulfation conditions. The target is to use the model for simulation of the lean/rich desulfation strategies, in order to comprehend the complicated phenomena and ultimately predict the sulfur speciation at the outlet of the NOx storage reduction catalyst. Sulfation tests in the presence and in the absence of O2 at different temperatures were conducted, in order to identify the different sulfation sites. Desulfation tests with constantly rich conditions and lean/rich oscillation, using H2 as the reducing gas, were performed in order to investigate the reaction pathways of the decomposition of the sulfates. Additionally, some preliminary investigation was performed using CO and decane in the reduc...