α‐Phase p‐Dichlorobenzene at 293K
1997
The α-phase structure of the title compound, C6H4C12, has been accurately redetermined at room temperature. Comparison with 100 K data shows that all different shortest intermolecular contacts (Cl...Cl, Cl... C, Cl...H, C...C, C...H, H...H) undergo thermal expansion. A three-centred hydrogen-bonding geometry is considered for some Cl...H contacts.
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