A Stereoselective Synthesis of the C20-C32 Fragment of the Phorboxazoles

J. S. Yadav,M. Satyanarayana,G. Srinivasulu,A. C. Kunwar

A Stereoselective Synthesis of the C20-C32 Fragment of the Phorboxazoles

2007

J. S. Yadav
M. Satyanarayana
G. Srinivasulu
A. C. Kunwar

The C20-C32 fragment of the phorboxazoles was realized in a stereoconvergent manner utilizing a desymmetrization approach. This successful strategy involves epimerization and modified Julia olefination as key steps.

Keywords:

Desymmetrization
Julia olefination
Epimer
Stereoselectivity
Stereochemistry
Chemistry
Organic chemistry

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