Asymmetric Conjugate Reduction of α,β-Unsaturated Esters with Chiral Rhodium(bisoxazolinylphenyl) Catalysts

Yasunori Tsuchiya,Yoshinori Kanazawa,Takushi Shiomi,Kazuki Kobayashi,Hisao Nishiyama

Asymmetric Conjugate Reduction of α,β-Unsaturated Esters with Chiral Rhodium(bisoxazolinylphenyl) Catalysts

2004

Yasunori Tsuchiya
Yoshinori Kanazawa
Takushi Shiomi
Kazuki Kobayashi
Hisao Nishiyama

Chiral rhodium(bisoxazolinylphenyl) complexes reduced α,β-unsaturated esters in high enantioselectivity up to 97-98% ee in the combination of alkoxyhydrosilanes.

Keywords:

Enantioselective synthesis
Catalysis
Conjugate
Hydrosilylation
Rhodium
Chemistry
Organic chemistry
Chirality (chemistry)

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