The effect of HIPS-g-MAH on the mechanical properties of PA66/PPO alloy

HIPS-g-MAH compatibilizer and the other three compatibilizers were prepared and added to the polyamide 66/polyphenylene oxide (PA66/PPO) alloy. The FT-IR spectra showed that the maleic anhydride (MAH) had successfully undergone grafting on the high impact polystyrene (HIPS). The effect of the MAH ratio in the HIPS-g-MAH compatibilizer, the HIPS-g-MAH compatibilizer weight ratio, and the PA66/PPO ratio on the mechanical properties of PA66/PPO alloy was systematically studied. The results showed that the PA66/PPO alloy possessed the optimal mechanical properties when the HIPS-g-MAH compatibilizer weight ratio was 7% and the MAH ratio in HIPS-g-MAH compatibilizer ranged 4% ~ 8%. The fracture morphologies of PA66/PPO alloy with different HIPS-g-MAH compatibilizer weight ratios were characterized by scanning electron microscope (SEM). The PA66/PPO alloy without HIPS-g-MAH compatibilizer showed a typical brittle fracture. The mechanical properties of PA66/PPO alloys with the HIPS-g-MAH compatibilizer were improved. In addition, the crystallization temperature of PA66/PPO alloy decreased with the increase in the HIPS-g-MAH compatibilizer weight ratio. The PA66/PPO ratio also played an essential role in the PA66/PPO alloy properties. The coefficient of friction and wear rate both increased with the increase in the PPO ratio.