Fabrication of micropillars on nanocellulose films using a roll-to-roll nanoimprinting method
2016
This paper presents a simple method to modify biobased nanocellulosic films with thermal roll-to-roll nanoimprinting lithography (R2RNIL) to produce microstructured films. In the NIL process a patterned roll and an elastic backing roll are pressed against each other at elevated temperatures, and the pattern is replicated onto the film structure. Here we demonstrate the fabrication of patterned nanocellulosic films prepared using mechanically disintegrated cellulose nanofibrils (CNF) and TEMPO-oxidised cellulose nanofibrils (TEMPO-CNF). Although both CNF films are brittle and nanocellulosic material itself is not thermoplastic with a clear softening point, it was shown that the mechanical patterning of both CNF films was possible. Imprinted pillar structures with a width of 7.5µm and a height of 1.5µm were achieved and both of the patterned CNF films showed a clear optical effect. The patterns are formed probably due to the compressibility of the CNF films and due to the film softening effect brought about by sorbitol, which is a commonly utilised softener for biopolymer films. In addition, the polyvinyl alcohol (PVA) used as a strength additive in the case of the films prepared using TEMPO-oxidised CNF possesses a thermoplastic feature. Distinct temperature dependency was observed with both films above 70°C. The height of the pillars increased almost linearly up to 155°C with a constant pressure of 8MPa. The temperature increase seems to improve the replication of the pillar shape. Simultaneously the nanoimprinting process smoothed the film surface roughness. Recovery and relaxation properties of the NIL-patterned CNF films were studied after one week. Height changes were as high as 36% for CNF film and 20% for TEMPO-CNF film. Roll-to-roll nanoimprinting patterned nanocellulosic films (CNF and TEMPO-CNF).AFM images of CNF and TEMPO-CNF films.Display Omitted Roll-to-roll imprinted structures in CNF films were demonstrated for the first time.Compressibility of CNF films due to high moisture was the main reason for successful patterning.Linear increase on pillar height when temperature was increased up to 155°C at constant pressure.Recovery and relaxation properties of CNF are relatively low.CNF shows a huge potential for future application in optics and electronics.
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