Novel reagents containing hypervalent iodine and their use for electrophilic additions to olefins

Nikolai S. Zefirov,Viktor V. Zhdankin,Yu. V. Dan'kov,V. D. Sorokin,V. N. Semerikov,A. S. Kozmin,R. Caple,Bruce Berglund

Novel reagents containing hypervalent iodine and their use for electrophilic additions to olefins

1986

Nikolai S. Zefirov
Viktor V. Zhdankin
Yu. V. Dan'kov
V. D. Sorokin
V. N. Semerikov
A. S. Kozmin
R. Caple
Bruce Berglund

Abstract A series of novel I(III) containing reagents have been developed and their electrophilic reactions with olefins giving vic -disubstituted derivatives (including vic -ditriflates) are described.

Keywords:

Iodine
Electrophile
Nucleophilic addition
Sulfonate
Ethylene
Reagent
Photochemistry
Aliphatic compound
Hypervalent molecule
Organic chemistry
Chemistry
Cyclohexene
Olefin fiber

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