Pyrano[3,4-c]pyrandiium dication
2020
Pyrano[3,4-c]pyrandiium dication has been detected in anhydrous D2SO4 using two-dimensional correlation NMR spectroscopy. The dication is generated as an intermediate in acid-catalyzed hydrolysis of 1-ethoxy-5-methyl-3,8-diphenyl-1H-pyrano[3,4-c]pyran-7-ium perchlorate, where the action of 70% HClO4 leads to the replacement of ethoxy group by hydroxyl one, and the reaction with SbCl5 affords dimeric bis(hexachloroantimonate) bearing two pyrano[3,4-c]pyran7-ium moieties linked via oxygen atom. The crystal structures of both isolated products have been determined.
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