Direct observation of modulation structure in room-temperature multiferroic Bi4.2K0.8Fe2O9+δ

2021 
Abstract The coexistence and coupling between alternatively stacked layers with different functional properties often give rise to exotic physical phenomena, such as high-temperature superconductivity, multiferroic behavior, and giant thermoelectric performance, which are tightly linked with the intrinsic microstructures. Here we unambiguously uncover the structural modulations in multiferroic Bi4.2K0.8Fe2O9+δ (BKFO) nanobelts with a magnetoelectric–dielectric superlattice by scanning transmission electron microscopy (STEM). The octahedrons in the perovskite layers are identified as FeO6 and the ordered arrangements of the Bi and K cations are clearly determined. Quantitative measurements of the positions of the Bi columns indicate that the displacive modulations can be decomposed into a transverse wave and a longitudinal wave, whose amplitudes and phases are layer-dependent. This study may help to understand and optimize the magnetoelectric coupling effect in BKFO.
    • Correction
    • Source
    • Cite
    • Save
    • Machine Reading By IdeaReader
    28
    References
    0
    Citations
    NaN
    KQI
    []