Complexes of 1,1,1-tris(diethylalumino)hexane with electron-donor compounds

1. Reaction of LiH and NaH with C5H11(AlEt2)3 gives the monohydride organoaluminum complexes M[C5H11C(AlEt2)3H]. 2. Reaction of KF with C5H11(AlEt2)3 affords the monofluoride organoaluminum complex K[C5H11(AlEt2)8F]. 3. Ether and pyridine give with C5H11C(AlEt2)3 complexes of compositions 1∶1, 1∶2, and 1∶3, but Et3N gives only the 1∶1 complex.