Crystal, electronic and magnetic structures of a novel series of intergrowth carbometalates R4Co2C3 (R = Y, Gd, Tb).
2021
A series of new ternary isostructural R4Co2C3 (R = Y, Gd, Tb) carbides was synthesized by annealing of arc-melted stoichiometric samples. The crystal structure of Tb4Co2C3 [space group P2/m, Pearson symbol mP18, a = 12.754(2) A, b = 3.6251(4) A, c = 7.0731(9) A, β = 105.601(6)°] was solved by direct methods from neutron powder diffraction data collected at 100 K. The room temperature unit cell parameters of the new phases were determined by X-ray powder diffraction technique. The crystal structure of Tb4Co2C3 is characterized as an intergrowth structure resulting from the stacking of alternating TbCoC (YCoC-type) and Tb2C (anti-CdCl2 type) fragments with a 2 : 1 ratio. Tb4Co2C3 orders ferromagnetically at TC = 35(1) K, whereas the isostructural Gd4Co2C3 reveals two magnetic transitions at TC1 = 82(3) K and TC2 = 13(2) K. Density functional theory (DFT) calculations confirm that the magnetic moments of the R4Co2C3 (R = Gd, Tb) carbides are exclusively due to the rare-earth elements. Y4Co2C3 is shown to be a Pauli-paramagnet by experimental and theoretical studies.
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