Preparation method for phenoxy ester in water phase
2011
The invention relates to a preparation method for phenoxy ester in a water phase. The phenoxy ester is prepared by reaction between phenol and an esterifying agent. The preparation method for the phenoxy ester in the water phase is characterized by comprising the following steps: adding the phenol to aqueous solution of sodium hydroxide or potassium hydroxide to prepare the sodium salt or the kali salt of the phenol; dropwise adding the esterifying agent under the condition of controlling the temperature to be 0-25 DEG C; keeping the temperature; after low-temperature action is performed for certain time, enabling the temperature to rise to 40-100 DEG C to continue the reaction; and after the reaction is ended, cooling and separating to prepare the phenoxy ester. The esterifying agent is cyanuric chloride, phosphorus oxychloride, phosphorus trichloride or acyl chloride. The preparation method for the phenoxy ester compound in the water phase has a simple the process, short reaction time, high product quality and high yield. In the reaction process, only water is used as a reaction solvent, an organic solvent is not adopted, and solvent recovery and aftertreatment do not need to be performed, thereby, the environment is protected.
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