Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts
2009
Chiral rhodium–bisoxazolinylphenyl acetate complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated carbonyl compounds with bis(pinacolato)diboron in the presence of sodium t-butoxide with enantioselectivity up to 97%.
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