27Al MAS NMR studies of a new polyoxyaluminium cluster and its selective transformation to five-coordinate aluminium in the solid state
1992
Solid state 27Al MAS NMR (MAS = magic angle spinning) studies of a new large polyoxyaluminium cluster cation provide insight into its structure, and show that thermal treatment at 850 °C yields a novel transitional aluminium oxide containing a metastable five-coordinate aluminium site.
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