Microstructural characteristics and degradation mechanism of the NiCrAlY/CrN/DSM11 system during thermal exposure at 1100 °C

To limit the elemental interdiffusion, a CrN diffusion barrier was introduced into the interface of NiCrAlY overlayer and DSM11 substrate. During vacuum heat treatment and thermal exposure, the single and continuous CrN barrier layer was first changed to the multilayer structure and then to the Ti-rich interlayer. With the gradual loss of continuity in the diffusion barrier, the elemental interdiffusion was accelerated. Due to the interdiffusion, the transformation of beta-NiAl -> gamma'-Ni(3)Al -> gamma-Ni and the low Al level occurred in the overlayer. The phase transformation of metastable theta-Al(2)O(3) to stable a and the accelerated elemental interdiffusion affected the integrity of the surface scales. After 100 h exposure at 1100 degrees C, the Al element was insufficient and the duplex coatings were degraded. (c) 2010 Elsevier B.V. All rights reserved.