Crystal structures of (R,R)-{[Ph(Me)CH]2NLi·pmdeta} and {[PhC(CH2)NH]Na·pmdeta}2: alkali metal amides derived from (R,R)-bis(α-methylbenzyl)amine
2001
The reaction of BunM (M = Li, Na) with
[(R,R)]-bis(α-methylbenzyl)amine in the presence of pmdeta
results in the formation of the chiral lithium amide complex
(R,R)-{[Ph(Me)CH]2NLi·pmdeta} and,
remarkably, the sodium enamide,
{[PhC(CH2)NH]Na·pmdeta}2;
both compounds have been authenticated by single crystal X-ray
diffraction.
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