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Enthalpy change of solution

The enthalpy of solution, enthalpy of dissolution, or heat of solution is the enthalpy change associated with the dissolution of a substance in a solvent at constant pressure resulting in infinite dilution.Dissolution by most gases is exothermic. That is, when a gas dissolves in a liquid solvent, energy is released as heat, warming both the system (i.e. the solution) and the surroundings. Dissolution can be viewed as occurring in three steps:The expressions of the enthalpy change of dissolution can be differential or integral, as function of the ratio of amounts solute-solvent.The enthalpy of mixing of an ideal solution is zero by definition but the enthalpy of dissolution of nonelectrolytes has the value of the enthalpy of fusion or vaporisation. For non-ideal solutions of electrolytes it is connected to the activity coefficient of the solute(s) and the temperature derivative of the relative permittivity.

[ "Enthalpy", "Aqueous solution", "Enthalpy of atomization", "isoperibol calorimeter", "Van 't Hoff equation" ]
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