Silver acetylide

Argentous percarbideSilver(1+) dicarbonSilver ethynideSilver acetylide is an inorganic chemical compound with the formula Ag2C2, a metal acetylide. The compound can be regarded as a salt of the weak acid, acetylene. The salt's anion consists of two carbon atoms linked by a triple bond. The alternate name 'silver carbide' is rarely used, although the analogous calcium compound CaC2 is called calcium carbide. Silver acetylide is an inorganic chemical compound with the formula Ag2C2, a metal acetylide. The compound can be regarded as a salt of the weak acid, acetylene. The salt's anion consists of two carbon atoms linked by a triple bond. The alternate name 'silver carbide' is rarely used, although the analogous calcium compound CaC2 is called calcium carbide. Pure silver acetylide is a heat- and shock-sensitive high explosive with the unusual property that on ignition it does not evolve any gas: A common misconception about the 'silver acetylide' used in commercial explosives is that it explodes without the evolution of gaseous products and that its chemical formula is Ag2C2. In reality, it is a double salt with the silver salt it was produced from, usually silver nitrate. The anion of the parent compound acts as the oxidizer in the decomposition reaction. The detonation velocity of the mixture silver acetylide: silver nitrate is 3460 m/s. That of pure silver acetylide is 4000 m/s. Other authors report values of only 1980 and 1200 m•s⁻¹ respectively. Silver acetylide can be produced by passing acetylene gas through a solution of silver nitrate: The reaction product is a greyish to white precipitate. This is the same synthesis from Berthelot in which he first found silver acetylide in 1866.