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Darmstadtium

Darmstadtium is a synthetic chemical element with the symbol Ds and atomic number 110. It is an extremely radioactive synthetic element. The most stable known isotope, darmstadtium-281, has a half-life of approximately 12.7 seconds. Darmstadtium was first created in 1994 by the GSI Helmholtz Centre for Heavy Ion Research near the city of Darmstadt, Germany, after which it was named. In the periodic table, it is a d-block transactinide element. It is a member of the 7th period and is placed in the group 10 elements, although no chemical experiments have yet been carried out to confirm that it behaves as the heavier homologue to platinum in group 10 as the eighth member of the 6d series of transition metals. Darmstadtium is calculated to have similar properties to its lighter homologues, nickel, palladium, and platinum. Darmstadtium was first created on November 9, 1994, at the Institute for Heavy Ion Research (Gesellschaft für Schwerionenforschung, GSI) in Darmstadt, Germany, by Peter Armbruster and Gottfried Münzenberg, under the direction of Sigurd Hofmann. The team bombarded a lead-208 target with accelerated nuclei of nickel-62 in a heavy ion accelerator and detected a single atom of the isotope darmstadtium-269: In the same series of experiments, the same team also carried out the reaction using heavier nickel-64 ions. During two runs, 9 atoms of 271Ds were convincingly detected by correlation with known daughter decay properties: Prior to this, there had been failed synthesis attempts in 1986–7 at the Joint Institute for Nuclear Research in Dubna (then in the Soviet Union) and in 1990 at the GSI. A 1995 attempt at the Lawrence Berkeley National Laboratory resulted in signs suggesting but not pointing conclusively at the discovery of a new isotope 267Ds formed in the bombardment of 209Bi with 59Co, and a similarly inconclusive 1994 attempt at the JINR showed signs of 273Ds being produced from 244Pu and 34S. Each team proposed its own name for element 110: the American team proposed hahnium after Otto Hahn in an attempt to resolve the situation on element 105 (which they had long been suggesting this name for), the Russian team proposed becquerelium after Henri Becquerel, and the German team proposed darmstadtium after Darmstadt, the location of their institute. The IUPAC/IUPAP Joint Working Party (JWP) recognised the GSI team as discoverers in their 2001 report, giving them the right to suggest a name for the element. Using Mendeleev's nomenclature for unnamed and undiscovered elements, darmstadtium should be known as eka-platinum. In 1979, IUPAC published recommendations according to which the element was to be called ununnilium (with the corresponding symbol of Uun), a systematic element name as a placeholder, until the element was discovered (and the discovery then confirmed) and a permanent name was decided on. Although widely used in the chemical community on all levels, from chemistry classrooms to advanced textbooks, the recommendations were mostly ignored among scientists in the field, who called it 'element 110', with the symbol of E110, (110) or even simply 110. In 1996, the Russian team proposed the name becquerelium after Henri Becquerel. The American team in 1997 proposed the name hahnium after Otto Hahn (previously this name had been used for element 105). The name darmstadtium (Ds) was suggested by the GSI team in honor of the city of Darmstadt, where the element was discovered. The GSI team originally also considered naming the element wixhausium, after the suburb of Darmstadt known as Wixhausen where the element was discovered, but eventually decided on darmstadtium. Policium had also been proposed as a joke due to the emergency telephone number in Germany being 1-1-0. The new name darmstadtium was officially recommended by IUPAC on August 16, 2003.

[ "Radiochemistry", "Nuclear physics", "Mass excess" ]
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