Carbon dioxide in Earth's atmosphere

Carbon dioxide (CO2) is an important trace gas in Earth's atmosphere. It is an integral part of the carbon cycle, a biogeochemical cycle in which carbon is exchanged between the Earth's oceans, soil, rocks and the biosphere. Plants and other photoautotrophs use solar energy to produce carbohydrate from atmospheric carbon dioxide and water by photosynthesis. Almost all other organisms depend on carbohydrate derived from photosynthesis as their primary source of energy and carbon compounds. CO2 absorbs and emits infrared radiation at wavelengths of 4.26 µm (asymmetric stretching vibrational mode) and 14.99 µm (bending vibrational mode) and consequently is a greenhouse gas that plays a significant role in influencing Earth's surface temperature through the greenhouse effect. Concentrations of CO2 in the atmosphere were as high as 4,000 parts per million by mass (ppm) during the Cambrian period about 500 million years ago to as low as 180 ppm during the Quaternary glaciation of the last two million years. Reconstructed temperature records for the last 420 million years indicate that atmospheric CO2 concentrations peaked at ~2000 ppm during the Devonian (∼400 Myrs ago) period, and again in the Triassic (220–200 Myrs ago) period. Global annual mean CO2 concentration has increased by more than 45% since the start of the Industrial Revolution, from 280 ppm during the 10,000 years up to the mid-18th century to 415 ppm as of May 2019. The present concentration is the highest for 14 million years. The increase has been attributed to human activity, particularly deforestation and the burning of fossil fuels. This increase of CO2 and other long-lived greenhouse gases in Earth's atmosphere has produced the current episode of global warming. Between 30% and 40% of the CO2 released by humans into the atmosphere dissolves into the oceans, wherein it forms carbonic acid and effects changes in the oceanic pH balance. Carbon dioxide concentrations have shown several cycles of variation from about 180 parts per million during the deep glaciations of the Holocene and Pleistocene to 280 parts per million during the interglacial periods. Following the start of the Industrial Revolution, atmospheric CO2 concentration increased to over 400 parts per million and continues to increase, causing the phenomenon of global warming. As of April 2019, the average monthly level of CO2 in Earth's atmosphere exceeded 413 parts per million. The daily average concentration of atmospheric CO2 at Mauna Loa Observatory first exceeded 400 ppm on 10 May 2013 although this concentration had already been reached in the Arctic in June 2012. As of 2010 it constitutes about 0.041% by volume of the atmosphere, (equal to 410 ppm) which corresponds to approximately 3200 billion metric tons of CO2, containing approximately 870 billion metric tons of carbon. Each part per million by volume of CO2 in the atmosphere thus represents approximately 2.13 billion metric tons of carbon. The global mean CO2 concentration is currently rising at a rate of approximately 2 ppm/year and accelerating. There is an annual fluctuation of about 3–9 ppm which is negatively correlated with the Northern Hemisphere's growing season. The Northern Hemisphere dominates the annual cycle of CO2 concentration because it has much greater land area and plant biomass than the Southern Hemisphere. Concentrations reach a peak in May as the Northern Hemisphere spring greenup begins, and decline to a minimum in October, near the end of the growing season. Since global warming is attributed to increasing atmospheric concentrations of greenhouse gases such as CO2, scientists closely monitor atmospheric CO2 concentrations and their impact on the present-day biosphere. The National Geographic wrote that the concentration of carbon dioxide in the atmosphere is this high 'for the first time in 55 years of measurement—and probably more than 3 million years of Earth history.' The current concentration may be the highest in the last 20 million years. Carbon dioxide concentrations have varied widely over the Earth's 4.54 billion year history. It is believed to have been present in Earth's first atmosphere, shortly after Earth's formation. The second atmosphere, consisting largely of nitrogen and CO2 was produced by outgassing from volcanism, supplemented by gases produced during the late heavy bombardment of Earth by huge asteroids. A major part of carbon dioxide emissions were soon dissolved in water and incorporated in carbonate sediments. The production of free oxygen by cyanobacterial photosynthesis eventually led to the oxygen catastrophe that ended Earth's second atmosphere and brought about the Earth's third atmosphere (the modern atmosphere) 2.4 billion years before the present. Carbon dioxide concentrations dropped from 4,000 parts per million during the Cambrian period about 500 million years ago to as low as 180 parts per million during the Quaternary glaciation of the last two million years. On long timescales, atmospheric CO2 concentration is determined by the balance among geochemical processes including organic carbon burial in sediments, silicate rock weathering, and volcanism. The net effect of slight imbalances in the carbon cycle over tens to hundreds of millions of years has been to reduce atmospheric CO2. On a timescale of billions of years, such downward trend appears bound to continue indefinitely as occasional massive historical releases of buried carbon due to volcanism will become less frequent (as earth mantle cooling and progressive exhaustion of internal radioactive heat proceed further). The rates of these processes are extremely slow; hence they are of no relevance to the atmospheric CO2 concentration over the next hundreds or thousands of years. In billion-year timescales, it is predicted that plant, and therefore animal, life on land will die off altogether, since by that time most of the remaining carbon in the atmosphere will be sequestered underground, and natural releases of CO2 by radioactivity-driven tectonic activity will have continued to slow down. The loss of plant life would also result in the eventual loss of oxygen. Some microbes are capable of photosynthesis at concentrations of CO2 of a few parts per million and so the last life forms would probably disappear finally due to the rising temperatures and loss of the atmosphere when the sun becomes a red giant some four billion years from now.