In organic chemistry, an electrophilic addition reaction is an addition reaction where, in a chemical compound, a π bond is broken and two new σ bonds are formed. The substrate of an electrophilic addition reaction must have a double bond or triple bond. In organic chemistry, an electrophilic addition reaction is an addition reaction where, in a chemical compound, a π bond is broken and two new σ bonds are formed. The substrate of an electrophilic addition reaction must have a double bond or triple bond. The driving force for this reaction is the formation of an electrophile X+ that forms a covalent bond with an electron-rich unsaturated C=C bond. The positive charge on X is transferred to the carbon-carbon bond, forming a carbocation during the formation of the C-X bond.