Petitgrain (pronounced ) is an essential oil that is extracted from the leaves and green twigs of the bitter orange tree (Citrus aurantium ssp. amara) via steam distillation. It is also known as petitgrain bigarade. Petitgrain (pronounced ) is an essential oil that is extracted from the leaves and green twigs of the bitter orange tree (Citrus aurantium ssp. amara) via steam distillation. It is also known as petitgrain bigarade.