Solomon equations

In NMR spectroscopy, the Solomon equations describe the dipolar relaxation process of a system consisting of two spins. They take the form of the following differential equations: In NMR spectroscopy, the Solomon equations describe the dipolar relaxation process of a system consisting of two spins. They take the form of the following differential equations: d I 1 z d t = − R z 1 ( I 1 z − I 1 z 0 ) − σ 12 ( I 2 z − I 2 z 0 ) {displaystyle {d{I_{1z}} over dt}=-R_{z}^{1}(I_{1z}-I_{1z}^{0})-sigma _{12}(I_{2z}-I_{2z}^{0})} d I 2 z d t = − R z 2 ( I 2 z − I 2 z 0 ) − σ 12 ( I 1 z − I 1 z 0 ) {displaystyle {d{I_{2z}} over dt}=-R_{z}^{2}(I_{2z}-I_{2z}^{0})-sigma _{12}(I_{1z}-I_{1z}^{0})} d I 1 z I 2 z d t = − R z 12 2 I 1 z I 2 z {displaystyle {d{I_{1z}I_{2z}} over dt}=-R_{z}^{12}2I_{1z}I_{2z}} These describe how the population of the different spin states changes in relation to the strength of the self-relaxation rate constant R and σ 12 {displaystyle sigma _{12}} , which accounts instead for cross-relaxation. The latter is the important term which is responsible for transferring magnetization from one spin to the other and gives rise to the nuclear Overhauser effect. In an NOE experiment, the magnetization on one of the spins, say spin 2, is reversed by applying a selective pulse sequence. At short times then, the resulting magnetization on spin 1 will be given by d I 1 z d t = − R z 1 ( I 1 z 0 − I 1 z 0 ) − σ 12 ( − I 2 z 0 − I 2 z 0 ) = 2 σ 12 I 2 z 0 {displaystyle {d{I_{1z}} over dt}=-R_{z}^{1}(I_{1z}^{0}-I_{1z}^{0})-sigma _{12}(-I_{2z}^{0}-I_{2z}^{0})=2sigma _{12}I_{2z}^{0}}