Space group

In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct. Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space.Arithmetic crystal classes may be interpreted as different orientations of the point groups in the lattice, with the group elements' matrix components being constrained to have integer coefficients in lattice space. This is rather easy to picture in the two-dimensional, wallpaper group case. Some of the point groups have reflections, and the reflection lines can be along the lattice directions, halfway in between them, or both.These correspond to conjugacy classes of lattice point groups in GLn(Z), where the lattice point group is the group of symmetries of the underlying lattice that fix a point of the lattice, and contains the point group. In mathematics, physics and chemistry, a space group is the symmetry group of a configuration in space, usually in three dimensions. In three dimensions, there are 219 distinct types, or 230 if chiral copies are considered distinct. Space groups are also studied in dimensions other than 3 where they are sometimes called Bieberbach groups, and are discrete cocompact groups of isometries of an oriented Euclidean space. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the International Tables for Crystallography (Hahn (2002)). Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list was complete was only given in 1891, after the much more difficult classification of space groups had been completed. In 1879 Leonhard Sohncke listed the 65 space groups (called Sohncke groups) whose elements preserve the orientation. More accurately, he listed 66 groups, but Fedorov and Schönflies both noticed that two of them were really the same. The space groups in three dimensions were first enumerated by Fedorov (1891) (whose list had two omissions (I43d and Fdd2) and one duplication (Fmm2)), and shortly afterwards were independently enumerated by Schönflies (1891) (whose list had four omissions (I43d, Pc, Cc, ?) and one duplication (P421m)). The correct list of 230 space groups was found by 1892 during correspondence between Fedorov and Schönflies. Barlow (1894) later enumerated the groups with a different method, but omitted four groups (Fdd2, I42d, P421d, and P421c) even though he already had the correct list of 230 groups from Fedorov and Schönflies; the common claim that Barlow was unaware of their work is a myth.Burckhardt (1967) describes the history of the discovery of the space groups in detail. The space groups in three dimensions are made from combinations of the 32 crystallographic point groups with the 14 Bravais lattices, each of the latter belonging to one of 7 lattice systems. This results in a space group being some combination of the translational symmetry of a unit cell including lattice centering, the point group symmetry operations of reflection, rotation and improper rotation (also called rotoinversion), and the screw axis and glide plane symmetry operations. The combination of all these symmetry operations results in a total of 230 different space groups describing all possible crystal symmetries. The elements of the space group fixing a point of space are the identity element, reflections, rotations and improper rotations. The translations form a normal abelian subgroup of rank 3, called the Bravais lattice. There are 14 possible types of Bravais lattice. The quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. Translation is defined as the face moves from one point to another point. A glide plane is a reflection in a plane, followed by a translation parallel with that plane. This is noted by a, b or c, depending on which axis the glide is along. There is also the n glide, which is a glide along the half of a diagonal of a face, and the d glide, which is a fourth of the way along either a face or space diagonal of the unit cell. The latter is called the diamond glide plane as it features in the diamond structure. In 17 space groups, due to the centering of the cell, the glides occur in two perpendicular directions simultaneously, i.e. the same glide plane can be called b or c, a or b, a or c. For example, group Abm2 could be also called Acm2, group Ccca could be called Cccb. In 1992, it was suggested to use symbol e for such planes. The symbols for five space groups have been modified: A screw axis is a rotation about an axis, followed by a translation along the direction of the axis. These are noted by a number, n, to describe the degree of rotation, where the number is how many operations must be applied to complete a full rotation (e.g., 3 would mean a rotation one third of the way around the axis each time). The degree of translation is then added as a subscript showing how far along the axis the translation is, as a portion of the parallel lattice vector. So, 21 is a twofold rotation followed by a translation of 1/2 of the lattice vector.