Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions. Chlorine (Cl−), fluorine (F−), and hydroxide (OH−) anions that also fit into the crystal structure. Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions. Chlorine (Cl−), fluorine (F−), and hydroxide (OH−) anions that also fit into the crystal structure.