Agricultural pollution

Agricultural pollution refers to biotic and abiotic byproducts of farming practices that result in contamination or degradation of the environment and surrounding ecosystems, and/or cause injury to humans and their economic interests. The pollution may come from a variety of sources, ranging from point source water pollution (from a single discharge point) to more diffuse, landscape-level causes, also known as non-point source pollution. Management practices play a crucial role in the amount and impact of these pollutants. Management techniques range from animal management and housing to the spread of pesticides and fertilizers in global agricultural practices. Agricultural pollution refers to biotic and abiotic byproducts of farming practices that result in contamination or degradation of the environment and surrounding ecosystems, and/or cause injury to humans and their economic interests. The pollution may come from a variety of sources, ranging from point source water pollution (from a single discharge point) to more diffuse, landscape-level causes, also known as non-point source pollution. Management practices play a crucial role in the amount and impact of these pollutants. Management techniques range from animal management and housing to the spread of pesticides and fertilizers in global agricultural practices. Pesticides and herbicides are applied to agricultural land to control pests that disrupt crop production. Soil contamination can occur when pesticides persist and accumulate in soils, which can alter microbial processes, increase plant uptake of the chemical, and are toxic to soil organisms. The extent to which the pesticides and herbicides persist depends on the compound’s unique chemistry, which affects sorption dynamics and resulting fate and transport in the soil environment. Pesticides can also accumulate in animals that eat contaminated pests and soil organisms. In addition, pesticides can be more harmful to beneficial insects, such as pollinators, and to natural enemies of pests (i.e. insects that prey on or parasitize pests) than they are to the target pests themselves. Pesticide leaching occurs when pesticides mix with water and move through the soil, ultimately contaminating groundwater. The amount of leaching is correlated with particular soil and pesticide characteristics and the degree of rainfall and irrigation. Leaching is most likely to happen if using a water-soluble pesticide, when the soil tends to be sandy in texture; if excessive watering occurs just after pesticide application; if the adsorption ability of the pesticide to the soil is low. Leaching may not only originate from treated fields, but also from pesticide mixing areas, pesticide application machinery washing sites, or disposal areas. Only a fraction of the nitrogen-based fertilizers is converted to produce and other plant matter. The remainder accumulates in the soil or lost as runoff. High application rates of nitrogen-containing fertilizers combined with the high water-solubility of nitrate leads to increased runoff into surface water as well as leaching into groundwater, thereby causing groundwater pollution. The excessive use of nitrogen-containing fertilizers (be they synthetic or natural) is particularly damaging, as much of the nitrogen that is not taken up by plants is transformed into nitrate which is easily leached. Nitrate levels above 10 mg/L (10 ppm) in groundwater can cause 'blue baby syndrome' (acquired methemoglobinemia). The nutrients, especially nitrates, in fertilizers can cause problems for natural habitats and for human health if they are washed off soil into watercourses or leached through soil into groundwater. Moreover, the abuse of fertilizers caused air pollution in the form of ammonia. The concentration of cadmium in phosphorus-containing fertilizers varies considerably and can be problematic. For example, mono-ammonium phosphate fertilizer may have a cadmium content of as low as 0.14 mg/kg or as high as 50.9 mg/kg. This is because the phosphate rock used in their manufacture can contain as much as 188 mg/kg cadmium (examples are deposits on Nauru and the Christmas islands). Continuous use of high-cadmium fertilizer can contaminate soil and plants. Limits to the cadmium content of phosphate fertilizers has been considered by the European Commission. Producers of phosphorus-containing fertilizers now select phosphate rock based on the cadmium content. Phosphate rocks contain high levels of fluoride. Consequently, the widespread use of phosphate fertilizers has increased soil fluoride concentrations. It has been found that food contamination from fertilizer is of little concern as plants accumulate little fluoride from the soil; of greater concern is the possibility of fluoride toxicity to livestock that ingest contaminated soils. Also of possible concern are the effects of fluoride on soil microorganisms. The radioactive content of the fertilizers varies considerably and depends both on their concentrations in the parent mineral and on the fertilizer production process. Uranium-238 concentrations range can range from 7 to 100 pCi/g in phosphate rock and from 1 to 67 pCi/g in phosphate fertilizers. Where high annual rates of phosphorus fertilizer are used, this can result in uranium-238 concentrations in soils and drainage waters that are several times greater than are normally present. However, the impact of these increases on the risk to human health from radinuclide contamination of foods is very small (less than 0.05 mSv/y). Steel industry wastes, which are recycled into fertilizers for their high levels of zinc (essential to plant growth), can include the following toxic metals: lead, arsenic, cadmium, chromium, and nickel. The most common toxic elements in this type of fertilizer are mercury, lead, and arsenic. These potentially harmful impurities can be removed; however, this significantly increases cost. Highly pure fertilizers are widely available and perhaps best known as the highly water-soluble fertilizers containing blue dyes used around households, such as Miracle-Gro. These highly water-soluble fertilizers are used in the plant nursery business and are available in larger packages at significantly less cost than retail quantities. There are also some inexpensive retail granular garden fertilizers made with high purity ingredients. The nitrogen (N) and phosphorus (P) applied to agricultural land (via synthetic fertilizers, composts, manures, biosolids, etc.) can provide valuable plant nutrients. However, if not managed correctly, excess N and P can have negative environmental consequences. Excess N supplied by both synthetic fertilizers (as highly soluble nitrate) and organic sources such as manures (whose organic N is mineralized to nitrate by soil microorganisms) can lead to groundwater contamination of nitrate. Nitrate-contaminated drinking water can cause blue baby syndrome. Together with excess P from these same fertilizer sources, eutrophication can occur downstream due to excess nutrient supply, leading to anoxic areas called dead zones.