Hollow-cathode lamp

A hollow-cathode lamp (HCL) is type of cold cathode lamp used in physics and chemistry as a spectral line source (e.g. for atomic absorption spectrometers) and as a frequency tuner for light sources such as lasers. An HCL takes advantage of the hollow cathode effect, which causes conduction at a lower voltage and with more current than a cold cathode lamp that does not have a hollow cathode. A hollow-cathode lamp (HCL) is type of cold cathode lamp used in physics and chemistry as a spectral line source (e.g. for atomic absorption spectrometers) and as a frequency tuner for light sources such as lasers. An HCL takes advantage of the hollow cathode effect, which causes conduction at a lower voltage and with more current than a cold cathode lamp that does not have a hollow cathode. An HCL usually consists of a glass tube containing a cathode, an anode, and a buffer gas (usually a noble gas). A large voltage across the anode and cathode will cause the buffer gas to ionize, creating a plasma. The buffer gas ions will then be accelerated into the cathode, sputtering off atoms from the cathode. Both the buffer gas and the sputtered cathode atoms will in turn be excited by collisions with other atoms/particles in the plasma. As these excited atoms decay to lower states, they will emit photons, which can then be detected and a spectrum can be determined. Either the spectrum from the buffer gas or the sputtered cathode material itself, or both, may be of interest. An HCL can also be used to tune light sources to a specific atomic transition by making use of the optogalvanic effect, which is a result of direct or indirect photoionization. By shining the light source into the HCL, one can excite or even eject electrons (directly photoionize) from the atoms inside the lamp, so long as the light source includes frequencies corresponding to the right atomic transitions. Indirect photoionization can then occur when electron collisions with the excited atom eject an atomic electron. A {displaystyle A} = atom, h ν {displaystyle h u } = photon, A ∗ {displaystyle A^{*}} = atom in excited state, and e − {displaystyle e^{-}} = electron