Magic angle

The magic angle is a precisely defined angle, the value of which is approximately 54.7356°. The magic angle is a root of a second-order Legendre polynomial, P2(cos θ) = 0, and so any interaction which depends on this second-order Legendre polynomial vanishes at the magic angle. This property makes the magic angle of particular importance in magic angle spinning solid-state NMR spectroscopy. In magnetic resonance imaging, structures with ordered collagen, such as tendons and ligaments, oriented at the magic angle may appear hyperintense in some sequences; this is called the magic angle artifact or effect. The magic angle is a precisely defined angle, the value of which is approximately 54.7356°. The magic angle is a root of a second-order Legendre polynomial, P2(cos θ) = 0, and so any interaction which depends on this second-order Legendre polynomial vanishes at the magic angle. This property makes the magic angle of particular importance in magic angle spinning solid-state NMR spectroscopy. In magnetic resonance imaging, structures with ordered collagen, such as tendons and ligaments, oriented at the magic angle may appear hyperintense in some sequences; this is called the magic angle artifact or effect. The magic angle θm is where arccos and arctan are the inverse cosine and tangent functions respectively.OEIS: A195696 θm is the angle between the space diagonal of a cube and any of its three connecting edges, see image. Another representation of the magic angle is half of the opening angle formed when a cube is rotated from its space diagonal axis, which may be represented as arccos −1/3 or 2 arctan √2 radians ≈ 109.4712°. This double magic angle is directly related to tetrahedral molecular geometry and is the angle between two vertices and the exact center of a tetrahedron (i.e., the edge central angle also known as the tetrahedral angle). In nuclear magnetic resonance (NMR) spectroscopy, three prominent nuclear magnetic interactions, dipolar coupling, chemical shift anisotropy (CSA), and first-order quadrupolar coupling, depend on the orientation of the interaction tensor with the external magnetic field.