Sulfur hydride

Hydrogen sulfide is the chemical compound with the formula H2S. It is a colorless chalcogen hydride gas with the characteristic foul odor of rotten eggs. It is very poisonous, corrosive, and flammable. Hydrogen sulfide is the chemical compound with the formula H2S. It is a colorless chalcogen hydride gas with the characteristic foul odor of rotten eggs. It is very poisonous, corrosive, and flammable. Hydrogen sulfide is often produced from the microbial breakdown of organic matter in the absence of oxygen gas, such as in swamps and sewers; this process is commonly known as anaerobic digestion which is done by sulfate-reducing microorganisms. H2S also occurs in volcanic gases, natural gas, and in some sources of well water. The human body produces small amounts of H2S and uses it as a signaling molecule. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, but this spelling is not recommended by the International Union of Pure and Applied Chemistry (IUPAC) or the Royal Society of Chemistry. Hydrogen sulfide is slightly denser than air; a mixture of H2S and air can be explosive. Hydrogen sulfide burns in oxygen with a blue flame to form sulfur dioxide (SO2) and water. In general, hydrogen sulfide acts as a reducing agent, especially in the presence of base, which forms SH−. At high temperatures or in the presence of catalysts, sulfur dioxide reacts with hydrogen sulfide to form elemental sulfur and water. This reaction is exploited in the Claus process, an important industrial method to dispose of hydrogen sulfide. Hydrogen sulfide is slightly soluble in water and acts as a weak acid (pKa = 6.9 in 0.01–0.1 mol/litre solutions at 18 °C), giving the hydrosulfide ion HS− (also written SH−). Hydrogen sulfide and its solutions are colorless. When exposed to air, it slowly oxidizes to form elemental sulfur, which is not soluble in water. The sulfide anion S2− is not formed in aqueous solution. Hydrogen sulfide reacts with metal ions to form metal sulfides, which are insoluble, often dark colored solids. Lead(II) acetate paper is used to detect hydrogen sulfide because it readily converts to lead(II) sulfide, which is black. Treating metal sulfides with strong acid often liberates hydrogen sulfide. At pressures above 90 GPa (gigapascal), hydrogen sulfide becomes a metallic conductor of electricity. When cooled below a critical temperature this high-pressure phase exhibits superconductivity. The critical temperature increases with pressure, ranging from 23 K at 100 GPa to 150 K at 200 GPa. If hydrogen sulfide is pressurized at higher temperatures, then cooled, the critical temperature reaches 203 K (−70 °C), the highest accepted superconducting critical temperature as of 2015. By substituting a small part of sulfur with phosphorus and using even higher pressures, it has been predicted that it may be possible to raise the critical temperature to above 0 °C (273 K) and achieve room-temperature superconductivity.