Mendelevium

Mendelevium is a synthetic element with the symbol Md (formerly Mv) and atomic number 101. A metallic radioactive transuranic element in the actinide series, it is the first element that currently cannot be produced in macroscopic quantities through neutron bombardment of lighter elements. It is the third-to-last actinide and the ninth transuranic element. It can only be produced in particle accelerators by bombarding lighter elements with charged particles. A total of sixteen mendelevium isotopes are known, the most stable being 258Md with a half-life of 51 days; nevertheless, the shorter-lived 256Md (half-life 1.17 hours) is most commonly used in chemistry because it can be produced on a larger scale.We thought it fitting that there be an element named for the Russian chemist Dmitri Mendeleev, who had developed the periodic table. In nearly all our experiments discovering transuranium elements, we'd depended on his method of predicting chemical properties based on the element's position in the table. But in the middle of the Cold War, naming an element for a Russian was a somewhat bold gesture that did not sit well with some American critics. Mendelevium is a synthetic element with the symbol Md (formerly Mv) and atomic number 101. A metallic radioactive transuranic element in the actinide series, it is the first element that currently cannot be produced in macroscopic quantities through neutron bombardment of lighter elements. It is the third-to-last actinide and the ninth transuranic element. It can only be produced in particle accelerators by bombarding lighter elements with charged particles. A total of sixteen mendelevium isotopes are known, the most stable being 258Md with a half-life of 51 days; nevertheless, the shorter-lived 256Md (half-life 1.17 hours) is most commonly used in chemistry because it can be produced on a larger scale. Mendelevium was discovered by bombarding einsteinium with alpha particles in 1955, the same method still used to produce it today. It was named after Dmitri Mendeleev, father of the periodic table of the chemical elements. Using available microgram quantities of the isotope einsteinium-253, over a million mendelevium atoms may be produced each hour. The chemistry of mendelevium is typical for the late actinides, with a preponderance of the +3 oxidation state but also an accessible +2 oxidation state. Owing to the small amounts of produced mendelevium and all of its isotopes having relatively short half-lives, there are currently no uses for it outside basic scientific research. Mendelevium was the ninth transuranic element to be synthesized. It was first synthesized by Albert Ghiorso, Glenn T. Seaborg, Gregory Robert Choppin, Bernard G. Harvey, and team leader Stanley G. Thompson in early 1955 at the University of California, Berkeley. The team produced 256Md (half-life of 77 minutes) when they bombarded an 253Es target consisting of only a billion (109) einsteinium atoms with alpha particles (helium nuclei) in the Berkeley Radiation Laboratory's 60-inch cyclotron, thus increasing the target's atomic number by two. 256Md thus became the first isotope of any element to be synthesized one atom at a time. In total, seventeen mendelevium atoms were produced. This discovery was part of a program, begun in 1952, that irradiated plutonium with neutrons to transmute it into heavier actinides. This method was necessary as the previous method used to synthesize transuranic elements, neutron capture, could not work because of a lack of known beta decaying isotopes of fermium that would produce isotopes of the next element, mendelevium, and also due to the very short half-life to spontaneous fission of 258Fm that thus constituted a hard limit to the success of the neutron capture process. To predict if the production of mendelevium would be possible, the team made use of a rough calculation. The number of atoms that would be produced would be approximately equal to the product of the number of atoms of target material, the target's cross section, the ion beam intensity, and the time of bombardment; this last factor was related to the half-life of the product when bombarding for a time on the order of its half-life. This gave one atom per experiment. Thus under optimum conditions, the preparation of only one atom of element 101 per experiment could be expected. This calculation demonstrated that it was feasible to go ahead with the experiment. The target material, einsteinium-253, could be produced readily from irradiating plutonium: one year of irradiation would give a billion atoms, and its three-week half-life meant that the element 101 experiments could be conducted in one week after the produced einsteinium was separated and purified to make the target. However, it was necessary to upgrade the cyclotron to obtain the needed intensity of 1014 alpha particles per second; Seaborg applied for the necessary funds. While Seaborg applied for funding, Harvey worked on the einsteinium target, while Thomson and Choppin focused on methods for chemical isolation. Choppin suggested using α-hydroxyisobutyric acid to separate the mendelevium atoms from those of the lighter actinides. The actual synthesis was done by a recoil technique, introduced by Albert Ghiorso. In this technique, the einsteinium was placed on the opposite side of the target from the beam, so that the recoiling mendelevium atoms would get enough momentum to leave the target and be caught on a catcher foil made of gold. This recoil target was made by an electroplating technique, developed by Alfred Chetham-Strode. This technique gave a very high yield, which was absolutely necessary when working with such a rare and valuable product as the einsteinium target material. The recoil target consisted of 109 atoms of 253Es which were deposited electrolytically on a thin gold foil. It was bombarded by 41 MeV alpha particles in the Berkeley cyclotron with a very high beam density of 6×1013 particles per second over an area of 0.05 cm2. The target was cooled by water or liquid helium, and the foil could be replaced. Initial experiments were carried out in September 1954. No alpha decay was seen from mendelevium atoms; thus, Ghiorso suggested that the mendelevium had all decayed by electron capture to fermium and that the experiment should be repeated to search instead for spontaneous fission events. The repetition of the experiment happened in February 1955. On the day of discovery, 19 February, alpha irradiation of the einsteinium target occurred in three three-hour sessions. The cyclotron was in the University of California campus, while the Radiation Laboratory was on the next hill. To deal with this situation, a complex procedure was used: Ghiorso took the catcher foils (there were three targets and three foils) from the cyclotron to Harvey, who would use aqua regia to dissolve it and pass it through an anion-exchange resin column to separate out the transuranium elements from the gold and other products. The resultant drops entered a test tube, which Choppin and Ghiorso took in a car to get to the Radiation Laboratory as soon as possible. There Thompson and Choppin used a cation-exchange resin column and the α-hydroxyisobutyric acid. The solution drops were collected on platinum disks and dried under heat lamps. The three disks were expected to contain respectively the fermium, no new elements, and the mendelevium. Finally, they were placed in their own counters, which were connected to recorders such that spontaneous fission events would be recorded as huge deflections in a graph showing the number and time of the decays. There thus was no direct detection, but by observation of spontaneous fission events arising from its electron-capture daughter 256Fm. The first one was identified with a 'hooray' followed by a 'double hooray' and a 'triple hooray'. The fourth one eventually officially proved the chemical identification of the 101st element, mendelevium. In total, five decays were reported up till 4 a.m. Seaborg was notified and the team left to sleep. Additional analysis and further experimentation showed the produced mendelevium isotope to have mass 256 and to decay by electron capture to fermium-256 with a half-life of 1.5 h. Being the first of the second hundred of the chemical elements, it was decided that the element would be named 'mendelevium' after the Russian chemist Dmitri Mendeleev, father of the periodic table. Because this discovery came during the Cold War, Seaborg had to request permission of the government of the United States to propose that the element be named for a Russian, but it was granted. The name 'mendelevium' was accepted by the International Union of Pure and Applied Chemistry (IUPAC) in 1955 with symbol 'Mv', which was changed to 'Md' in the next IUPAC General Assembly (Paris, 1957). In the periodic table, mendelevium is located to the right of the actinide fermium, to the left of the actinide nobelium, and below the lanthanide thulium. Mendelevium metal has not yet been prepared in bulk quantities, and bulk preparation is currently impossible. Nevertheless, a number of predictions and some preliminary experimental results have been done regarding its properties.