Yong‐Min Liang

Lanzhou University

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Xue‐Yuan Liu

Lanzhou University

235

Yi‐Feng Qiu

Xinjiang University

139

Xue‐Yuan Liu

Lanzhou University

129

Xian‐Rong Song

Jiangxi Science and Technology Normal University

102

Ke‐Gong Ji

Northwest A&F University

Bo‐Sheng Zhang

Northwest Normal University

Yu‐Tao He

Jinan University

Xue‐Ya Gou

Lanzhou University

Xing‐Zhong Shu

Lanzhou University

Feng Zhou

Chinese Academy of Sciences

Cooperative Institutions

Lanzhou University

314

Chinese Academy of Sciences

298

Lanzhou Institute of Chemical Physics

165

University of Chinese Academy of Sciences

148

Lanzhou City University

112

Northwest Normal University

Zhejiang University

Shanghai Jiao Tong University

State Key Laboratory of Applied Organic Chemistry

Sun Yat-sen University

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Palladium-catalyzed intramolecular tandem dearomatization of indoles for the synthesis of tetracyclic indolines

Arabian Journal of Chemistry (2021)

Shao-Bo Duan Xu-Jing Gao Hong‐Yu Zhang Congcong Lu Jiquan Zhao

A highly diastereoselective, atom-economical, and palladium-catalyzed Heck protocol for the assembly of structurally diverse indoline scaffolds with vicinal tertiary as well as quaternary stereocenters is described, starting from readily available N-halobenzoyl o-haloaniline derivatives and phenylboronic acids. This cascade annulation reaction, which is scalable and conducts under an ambient atmosphere, provides the valuable tetracyclic indoline derivatives in an efficient and straightforward way.

Indoline

Stereocenter

Annulation

Tandem

Cascade reaction

Vicinal

Methylenedioxy

Phenylboronic acid

10.1016/j.arabjc.2021.103155

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Citations (9)

CCDC 2141478: Experimental Crystal Structure Determination

The Cambridge Structural Database (2023)

Xue‐Ya Gou Yuke Li Wei‐Yu Shi Yu‐Yong Luan Yanan Ding

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccdc.csd.cc29wcyj

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Citations (0)

CCDC 2243644: Experimental Crystal Structure Determination

The Cambridge Structural Database (2023)

Xi Chen Zhe Zhang Wei‐Yu Shi Yanan Ding Yu‐Yong Luan

10.5517/ccdc.csd.cc2f9pm2

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Citations (0)

Copper‐Catalyzed C–P Coupling through Decarboxylation

Chemistry - A European Journal (2011)

Jie Hu Ning Zhao Bin Yang Ge Wang Li‐Na Guo

An acid for a phosphine: A versatile protocol for preparation of various di(phenyl)phosphoryl oxides was developed by copper-catalyzed decarboxylative coupling of alkenyl, alkynyl carboxylic acids, and N-benzylproline, respectively, with R2P(O)H (see scheme). All classes of products are important precursors for preparation of biologically active molecules and various phosphorus ligands. This finding represents the first example of copper-catalyzed decarboxylative coupling to construct CP bonds. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

Decarboxylation

10.1002/chem.201003561

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Citations (212)

Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes

Organic Letters (2013)

Yu‐Tao He Lianhua Li Yan‐Fang Yang Zhao‐Zhao Zhou Hui‐Liang Hua

A novel and highly practical reaction for the copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes is presented here. This methodology provides a general and straightforward way to synthesize a variety of useful CF3-containing nitriles, which can be used for further preparation of pharmaceutically and agrochemically important compounds in synthetic organic chemistry.

Organic Synthesis

10.1021/ol403263c

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Citations (147)

A Novel Iron-Catalyzed Decarboxylative Csp³−Csp² Coupling of Proline Derivatives and Naphthol

Organic Letters (2009)

Hai‐Peng Bi Wenwen Chen Yong‐Min Liang Chao‐Jun Li

A novel iron-catalyzed intermolecular decarboxylative Csp(3)-Csp(2) coupling reaction using proline derivatives as starting materials is developed. In this process, a series of potentially useful ligands (tertiary aminonaphthol) for catalysis was obtained.

10.1021/ol901129v

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Citations (143)

Copper-catalyzed synthesis of trifluoromethyl-substituted isoxazolines

Chemical Communications (2013)

Yu‐Tao He Lianhua Li Yan‐Fang Yang Yuqi Wang Jianyi Luo

A mild and efficient copper-catalyzed trifluoromethylation reaction which involves the cyclization of oximes has been developed. This method provides a convenient access to a variety of useful CF3-containing 4,5-dihydroisoxazoles by constructing a C–CF3 bond and a C–O bond in one step.

Trifluoromethylation

10.1039/c3cc42588f

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Citations (144)

AN ALTERNATIVE SYNTHESIS OF LONG-CHAIN ALKYLFERROCENE DERIVATIVES

Synthetic Communications (2001)

Shengjun Luo Chao‐Min Liu Yong‐Min Liang Yongxiang Ma

An alternative synthesis of alkyl ferrocene derivatives by reduction of α-ferrocenylthiophene or -α-polythiophenes derivatives in the presence of fresh prepared Raney Ni was described. Six alkylferrocenes including three new products were synthesized and determined by NMR, IR and MS analysis.

Proton NMR

Raney nickel

10.1081/scc-100105885

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Citations (3)

MICROWAVE-ASSISTED SYNTHESIS OF SUBSTITUTED CYCLOPROPYL, FERROCENYL KETONES BY A SULFUR YLIDE REACTION UNDER SOLID-STATE CONDITIONS

Organic Preparations and Procedures International (2002)

Qihai Xu Baohua Chen Yongxiang Ma Wanyi Liu Yong‐Min Liang

Ylide

10.1080/00304940209355758

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Citations (3)

Palladium-Catalyzed ortho-C–H Glycosylation/ipso-Alkenylation of Aryl Iodides

The Journal of Organic Chemistry (2020)

Yanan Ding Wei‐Yu Shi Ce Liu Nian Zheng Ming Li

This report describes the first example of palladium-catalyzed ortho-C–H glycosylation/ipso-alkenylation of aryl iodides, and the easily accessible glycosyl chlorides are used as a glycosylation reagent. The reaction is compatible with the functional groups of the substrates, and a series of C-aryl glycosides have been synthesized in good to excellent yield and with excellent diastereoselectivity. It is found that a cheap 5-norbornene-2-carbonitrile as a transient mediator can effectively promote this reaction. In addition, ipso-arylation and cyanation were also realized by the strategy.

Norbornene

10.1021/acs.joc.0c01392

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Citations (47)