Hydroclimate evolution history and changes in the Tibetan Plateau play significant roles in depicting paleoclimate and evaluating climatic conditions in the coming future. However, the interaction of the westerlies and the Asian monsoon complicates our understanding of the mechanism of climate variation over the Tibetan Plateau. In this study, we assessed the paleoclimate of Hurleg Lake, which was previously located in the convergence area of the East Asian monsoon and westerly wind. We first reconstructed the climatic conditions based on fined-grained authigenic carbonate δ 18 O (δ 18 O carb ), plant-derived proxies of C/N, and n -alkane-derived δ 13 C 31 . In the Hurleg Lake, δ 18 O carb was controlled by δ 18 O changes of the lake water and evaporation. The climate evolution since ∼16.1 cal kyr BP can be classified into three stages. The Lateglacial (16.1–11.0 cal kyr BP) was characterized by a warm-wet climate in the beginning, followed by a cold-dry climate since 12.0 cal kyr BP. Typical warm and cold phases occurred during 14.8–12.0 cal kyr BP and 12.0–11.1 cal kyr BP, which may correspond to the Bølling/Allerød (B/A) and Younger Dryas periods, respectively. The early to mid-Holocene was generally characterized by a warm-wet climate; however, notable cold-dry intervals occurred at ∼8.3 cal kyr BP. The Late Holocene (after 4.8 cal kyr BP) displayed a significantly cold-wet climate. Finally, we examined the possible mechanisms responsible for the climate variability in the study area. The results showed that the long-term warm trend in the Lateglacial and colder trend after early Holocene was controlled by insolation. The Asian summer monsoon and the westerlies played a significant role in determining moisture sources during the Lateglacial. The East Asian monsoon contributed greatly to the moisture variation from the early to mid-Holocene, whereas the westerly winds dominated during the late Holocene. Combined, our findings highlight the complex changes in hydroclimate conditions since the last glacial in the Tibetan Plateau and provide crucial implications for comprehending the hydroclimate pattern in the transition zone of westerlies and Asian monsoon.
Long-chain alkyl diols (LCDs) can be used as organic geochemical proxies for paleoceanographic change, especially in marginal sea areas where large volumes of sediments are deposited rapidly and continuously. However, little is known about the applicability and response on a millennium scale in relation with existing records in those sediments. We reconstruct changes in upwelling and terrestrial organic matter (OM) input in core sediments from the Zhejiang Fujian coastal station (T08) and Yangtze River Estuary station (T06) in the inner shelf of the East China Sea (ECS) over the last millennium, using the LCD based proxies: diol index 2 (DI-2), and FC 32 1,15-diol. Our results show that DI-2 values ([(C 28 +C 30 )1,14-diols]/([(C 28 +C 30 )1,13-diols]+[(C 28 +C 30 )1,14-diols])) at T08 decrease significantly during 600–400 yr BP but increase gradually after 400 yr BP. The FC 32 1,15-diol proxy ([C 32 1,15-diol]×100/([(C 28 +C 30 )1,13-diols]+[(C 30 +C 32 )1,15-diols])) at T06 shows marked fluctuations during 1000–800 yr BP, followed by a significant decline during 800–500 yr BP but a subsequent increase from 500 to 300 yr BP. We find that variations in DI-2 values are broadly consistent with changes in the strength of the East Asian Summer Monsoon (EASM) and the Kuroshio Current and are likely linked to changes in the frequency and intensity of the El Niño-Southern Oscillation (ENSO). The increased strength of the EASM causes greater offshore movement of the upper layer of seawater, which in turn triggers upwelling of bottom waters formed by Kuroshio subsurface waters. We find that variations in FC 32 1,15-diol proxy are controlled mainly by the East Asian Winter Monsoon (EAWM) and the Yangtze River discharge. By increasing the strength of the EAWM, southward transportation of material deposited in the estuary of the Yangtze River by the ECS coastal currents is promoted. In addition, we synthesize records of other organic geochemical indicators nearby core sediments in the ECS; these records emphasize the importance of reconstructing the evolutionary history of upwelling and subdividing the relative inputs of terrestrial OM. Our study provides a new means for reconstructing the evolution of upwelling and terrestrial OM input in the inner shelf of the ECS over the last millennium.
The impacts of anthropogenic emissions on the reduction of source-specific equivalent black carbon (eBC) aerosol and their direct radiative effects (DREs) were investigated during the lockdown of coronavirus outbreak in a megacity of China in 2020. Five eBC sources were identified by a newly developed hybrid environmental receptor model. Results showed that biomass burning, traffic-related emissions, and coal combustion were the dominant contributors to eBC. The generalized addictive model indicated that the reduction of traffic-related eBC during the lockdown was entirely attributed to the decrease of emission. The decreased biomass-burning activities and favorable meteorological factors are both important drivers for the biomass-burning eBC reduction during the lockdown. A radiative transfer model showed that the eBC DRE efficiency of biomass burning was the strongest, followed by coal combustion and traffic-related emissions. This study highlights that aggressive reduction in the consumption of residential solid fuels would be effective on climate change mitigation.
Methylglyoxal (MGLY) plays a significant role in atmospheric chemistry by serving as a key contributor to the formation of active free radicals, ozone, and secondary organic aerosol. Detection of MGLY by traditional chemical ionization such as proton-transfer reaction has several shortcomings such as parent molecule fragmentation. In this study, an electron attachment reaction (EAR) ionization method has been developed for the effective detection of MGLY. Almost no fragmentation was observed during the EAR. The generation of MGLY- anion in the EAR was further confirmed by cryogenic photoelectron imaging spectroscopy. The concentration of MGLY can be calibrated by using dibromomethane (CH2Br2) as reference gas. The detection sensitivity of MGLY was estimated to be (100 ± 2) mV/ppbv (parts per billion by volume). The O2, H2O, CO2, and trace gases in ambient air have no obvious effects on the detection of MGLY- anion by the EAR ionization method.
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