An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
The first polyoxometalate (POM)-encapsulated twenty-four-nucleus organophosphorus-copper nanocage cluster organic framework has been constructed. Here, the phosphomolybdate POMs were incorporated into an octahedral nanocage cluster organic framework, and the resulting material exhibited highly efficient bifunctional electrochemical performance. The crystalline material showed a high specific capacitance of 366.3 F g-1 at a current density of 3 A g-1.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
Per- and poly-fluoroalkyl substances (PFASs) as emergent contaminants are generating serious environmental and health issues. An imminent task is thus to develop effective technologies to completely remove and ideally decompose PFASs through physical and/or chemical routes. Heterogeneous photocatalysis, which directly utilizes sunlight to drive the chemical decomposition of many organic compounds, is a promising solution to remediating PFASs-contaminated environment. In this review, the current progress of heterogeneous photocatalytic technology for decomposing PFASs is systematically summarized. The significance of environmental factors during heterogeneous photocatalysis is discussed from three aspects including anaerobic vs aerobic, acidic vs alkaline, and light use vs light loss. The associated reaction mechanisms and reaction routes are analyzed based on the stepwise change of PFASs molecular structures. Some further issues regarding PFASs heterogeneous photocatalysis are briefly pointed out along with the potential industrial applications of this technology.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.