Qin‐Yu Zhu

Soochow University

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Jie Dai

Hunan University of Traditional Chinese Medicine

405

Guo‐Qing Bian

Chinese Academy of Sciences

141

Jie Dai

Beijing University of Posts and Telecommunications

Jin-Le Hou

Liaocheng University

Peng Huo

Xinjiang Technical Institute of Physics & Chemistry

Dingxian Jia

Soochow University

Wen Luo

Shanghai University

Yi-Gang Weng

Soochow University

Jin-Po Wang

Soochow University

Yu-Rong Qin

Guangdong Academy of Medical Sciences

Cooperative Institutions

Soochow University

109

Chinese Academy of Sciences

Nanjing University

Suzhou Research Institute

University of Chinese Academy of Sciences

Central South University

State Council of the People's Republic of China

Xi'an Jiaotong University

Harbin Institute of Technology

Sichuan University

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Ln-Mof and its Hydrogel Composite Ln-Mof@Pva for Dual-Luminescence Ratiometric Temperature Sensing

Xu-Sheng Gao Qian Sun Xin Sui Qin‐Yu Zhu Shanshan Zhu

In this study, we synthesized a solid solution of MOF, Eu0.05Y0.95-PTC (H3PTC represents 2, 4, 6-pyridine tricarboxylic acid) by hydrothermal reaction, which showed exceptional stability under both weakly acidic and alkaline conditions and multiband luminescence. We further prepared Eu0.05Y0.95-PTC@PVA hydrogels by immobilizing Eu0.05Y0.95-PTC into a polyvinyl alcohol (PVA) aqueous solution, which exhibited both the integrity and temperature sensing behavior of the MOF solid solution, alongside excellent mechanical performance. Both Eu0.05Y0.95-PTC and Eu0.05Y0.95-PTC@PVA-8 hydrogel displayed temperature sensing capabilities over the range from 303 to 383 K, with relative sensitivities (Sr) reaching a maximum value of 2.81%•K−1 and 1.16%•K−1 at 383 K, respectively, and good recyclability as well.

Composite film

10.2139/ssrn.4556093

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CCDC 2192252: Experimental Crystal Structure Determination

The Cambridge Structural Database (2023)

Zhi-Ruo Zhang Zhouhong Ren Chen-Yue Luo Lijun Ma Jie Dai

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccdc.csd.cc2cl6t0

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CCDC 1500771: Experimental Crystal Structure Determination

Chong-Jiao Mo Zhaoqi Li Chen-Jie Que Guang-Lin Zhang Qin‐Yu Zhu

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CCDC 1499910: Experimental Crystal Structure Determination

Ting Chen Peng Huo Jin-Le Hou Jing Xu Qin‐Yu Zhu

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CCDC 656549: Experimental Crystal Structure Determination

Jing Gu Qin‐Yu Zhu Yong Zhang Wen Lu Gai-Yan Niu

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CCDC 2063076: Experimental Crystal Structure Determination

The Cambridge Structural Database (2021)

Wen‐Yu Yin Yi-Gang Weng Zhouhong Ren Zhi-Ruo Zhang Qin‐Yu Zhu

10.5517/ccdc.csd.cc277sv4

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New Chalcogenidoarsenates with Transition Metal Complex Cations: [M(en)₃]₂As₂S₅ (M: Mn, Ni) and [Mn(en)₃]₂As₂Se₅.

ChemInform (2006)

Dingxian Jia Qianxin Zhao Jie Dai Yong Zhang Qin‐Yu Zhu

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

10.1002/chin.200612023

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C–C to CC conversion within a supramolecular framework of tetrathiafulvalene: a confinement effect and an oxygen related dehydrogenation

Chemical Communications (2018)

Ping Zhang Peng Huo Xuan Zhang Qin‐Yu Zhu Jie Dai

Dehydrogenation of alkanes to generate alkenes is catalyzed by a supramolecular framework of a tetrathiafulvalene derivative under ambient conditions, and a confinement effect of the framework is responsible for the oxidation reaction in the presence of oxygen.

Tetrathiafulvalene

10.1039/c8cc03197e

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Synthesis and crystal structure of aluminium complex with 3-hydroxyflavone

Yanfang Wu B. Zhang Qin‐Yu Zhu Zhi‐Yong Wu Yu‐Hua Lin

[Al(C15H9O3)(3)](2) . 2CHCl(3) . 8H(2)O was synthesized, and its crystal structure was determined. It belongs to trigonal system, R3, a=b=1. 655 8(3) nm, c=3. 646 5(20) nm, alpha = beta = 90 degrees, gamma = 120 degrees, V = 8. 656 08(0. 005 86) nm(3). D-c = 1.45 g/cm(3), mu(Mo K alpha) = 3. 20 cm(-1), F (000) = 3 924. The crystal structure was solved by Patterson and Fourier techniques, and refined by a block-diagonal least-squares method. A total of 3 737 independent intensity data were collected, of which 1 033 with I greater than or equal to 3 sigma(I-0) were observed, R = 0. 091 8, Rw=0. 091 8. Al3+ ion was 6-coordinated, bound to six oxygen atoms from three 3-hydroxyflavones to form a distortional coordination octahedron.

Crystal (programming language)

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Metal centered oxidation or ligand centered oxidation of metal dithiolene? Spectral, electrochemical and structural studies on a nickel-4-pyridine-1,2-dithiolate system

Physical Chemistry Chemical Physics (2013)

Xinyu Li Yonggang Sun Peng Huo Ming-Yan Shao Shufang Ji

The complex Et4N[Ni(4-pedt)2] (1) (4-pedt = 1-(pyridine-4-yl) ethylene-1,2-dithiolate) was synthesized to investigate the behaviour of metal dithiolene compounds upon protonation and oxidation by absorption spectroscopy, electrochemistry and structural analyses and to further understand the electronic states of the dithiolene compounds. It is unexpected that the 915 nm NIR transition band is not shifted when H+ is added, and it is only affected (blue-shifted) when the compound is oxidized. All the evidence of electronic spectra indicates that the NIR band is relevant to the central [Ni(edt)2] moiety (edt = ethylenedithiolate), not the behaviour of individual Ni ions or ligands. It is also not the band of intermolecular interaction of a dimer. The moderately intense band appearing at 655 nm upon protonation is assigned to the intramolecular charge-transfer band between the [Ni(edt)2] moiety and the pyridine. The redox potentials of the metal dithiolene are sensitive to the protonation of the pyridyl group. The structures of monocationic complex 1 and the protonated compounds [Ni(4-Hpedt)2]·ClO4·H2O (2) and [Ni(4-Hpedt)2]·PhSO3·2DMF (3) were characterized by single crystal X-ray determination. The structural data demonstrate that the oxidation of the monoanionic dithiolene complex to neutral does not change the Ni–S bond distances obviously, which further indicates that the process is not only the metal centered oxidation.

Moiety

10.1039/c3cp44054k

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Citations (21)