There has been significant interest in using electronically contacted nanorod or nanotube arrays as gas sensors, whereby an adsorbate modifies either the impedance or the Fermi level of the array, enabling detection. Typically, such arrays demonstrate the I–V curves of a Schottky diode that is formed using a metal–semiconductor junction with rectifying characteristics. We show in this work that nanostructured Schottky diodes have a functionally different response, characteristic of the large electric field induced by the size scale of the array. Specifically, they are characterized by a low reverse breakdown voltage. As a result, the reverse bias current becomes a strong function of the applied voltage. In this work, for the first time, we model this unique feature by describing the enhancement effect of high aspect ratio nanostructures on the I–V characteristics of a Schottky diode. A Pt/ZnO/SiC nanostructured Schottky diode is fabricated to verify the theoretical equations presented. The gas sensing properties of the Schottky diode in reversed bias is investigated and it is shown that the theoretical calculations are in excellent agreement with measurements.
Polyaniline (PANI) is one of the most studied conducting polymers. Obtained in its conducting form (known as "emeraldine salt") by chemical or electrochemical oxidation of aniline in aqueous acidic medium, this polymer manifests an array of attractive properties. In our work, we investigate the properties of PANI in the form of nanofibers and establish the relationship between the level of doping, optical properties and the conductivity. Two methodologies, chemical and electro-chemical polymerization were used to deposit PANI. In former, dedoped PANI was deposited as a thin film on the glass substrate which was then doped with different concentrations of hydrochloric acid (HCl) to observe the change in conductivity and color. UV-Visible spectra (transmittance and absorbance) of the films were acquired and their conductivities were measured using a four-probe setup. In the latter method, PANI in the emeraldine salt form were deposited on ITO glass using an electrolytic cell. The voltage, temperature and electrolytic environment were varied to analyze the effect of change of doping levels on the optical and electrical properties of PANI. Surface electron microscope images were also taken which showed the nanofibers possessing circular cross sections in the order of 30-60 nm.
Novel Love mode filters based on ZnO and SiO/sub 2//90/spl deg/ rotated ST-cut quartz crystal structure were fabricated. A comprehensive study was carried out to show the capabilities of such filters. The periodicity of the fingers is 50 /spl mu/m and the thickness of the SiO/sub 2/ and ZnO layers ranges from 0.2 to 7.2 /spl mu/m. Electromechanical coupling coefficient, capacitance per unit wavelengths of finger pairs and temperature coefficient of frequency are studied in terms of thickness of the wave-guiding layers.
International competition among copper wire suppliers increased the demand for automatic surface inspection equipment. The authors critically review a range of existing surface inspection techniques and describe preliminary results on a new system.
Layered Surface Acoustic Wave (SAW) transducers were fabricated and modelled by finite-element method. A comparison of the frequency response of the measured devices and simulated structures are presented. The transducer structure is based on a two-port delay line, employing x-cut, y-propagating lithium niobate (LiNbO/sub 3/) substrate and a thin film zinc oxide (ZnO) guiding layer. A finite-element approach was employed to simulate a 3-dimensional version of the fabricated device. A transient analysis was conducted, where electrical and mechanical boundary values were applied. Simulation results show good agreement with experimental results, indicating that a finite-element approach is appropriate for modelling layered SAW transducers.