Mingdong Zhou

Shenyang University of Chemical Technology

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Shuliang Zang

Quanzhou Normal University

Fritz E. Kühn

Technical University of Munich

Jing Sun

Southwest Medical University

Xiangchen Fang

Sinopec (China)

Jingyun Wang

Jingdezhen Ceramic Institute

Liangliang Huang

Liaoning Shihua University

Ruixia Xie

Southern Medical University

Zhizhi Zhang

Lanzhou Institute of Chemical Physics

Shanshan Li

Institute of Biophysics

Eberhardt Herdtweck

Technical University of Munich

Cooperative Institutions

Liaoning Shihua University

Chinese Academy of Sciences

Technical University of Munich

Fudan University

University of Chinese Academy of Sciences

Shenyang University of Chemical Technology

Dalian University of Technology

Nanyang Normal University

University of Science and Technology of China

Tsinghua University

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Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts

Green Chemistry (2014)

Mingdong Zhou Meiju Liu Liangliang Huang Jian Zhang Jingyun Wang

Alkylimidazolium/alkylpyridinium octamolybdates can be used as self-separating catalysts in acetonitrile-mediated olefin epoxidations using hydrogen peroxide as oxidant.

10.1039/c4gc01411a

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Citations (47)

Bidentate Lewis Base Adducts of Methyltrioxidorhenium(VII): Ligand Influence on Catalytic Performance and Stability

European Journal of Inorganic Chemistry (2009)

Mingdong Zhou Kavita R. Jain Alev Günyar Paul N. W. Baxter Eberhardt Herdtweck

Abstract Methyltrioxidorhenium (MTO) forms 1:1 adducts of the general formula CH 3 ReO 3 · L 2 with bidentate Lewis bases (L 2 = 5,5′‐dimethyl‐2,2′‐bipyridine, 5,5′‐diamino‐2,2′‐bipyridine, 4,4′‐dibromo‐2,2′‐bipyridine, 5,5′‐dibromo‐2,2′‐bipyridine, diethyl 2,2′‐bipyridine‐5,5′‐dicarboxylate, 1,10‐phenanthroline‐5,6‐dione, 3,6‐di(2‐pyridyl)pyridazine). Due to the steric demands of the ligands, the complexes display a distorted octahedral geometry as confirmed by solid state X‐ray crystallography. The rhenium center is disordered in all examined crystal structures. The complexes synthesized are thermally stable but sensitive to light and moisture. The 2,2′‐bipyridine derived complexes exhibit good catalytic activities for cyclooctene epoxidation in a biphasic H 2 O 2 /organic solvent catalytic system using hydrogen peroxide as oxidizing agent. The functional groups on the bipyridine rings play an important role with respect to the differences in formation, stability and activity of the complexes. Their influence depends largely on their electron donor capabilities. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

Bipyridine

2,2'-Bipyridine

Pyridazine

Cyclooctene

10.1002/ejic.200900260

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Citations (34)

CCDC 1413845: Experimental Crystal Structure Determination

The Cambridge Structural Database (2016)

Shanshan Li Jing Sun Zhizhi Zhang Ruixia Xie Xiangchen Fang

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/ccdc.csd.cc1jg6x3

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Citations (0)

A three-dimensional zincophilic layer for dendrite-free zinc metal anodes

Journal of Energy Storage (2024)

Zhe Gong Qiushi Jiang Yu Han Yuanyuan Ma Pengfei Wang

Dendrite (mathematics)

10.1016/j.est.2024.111530

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Citations (3)

Pale yellow-to-dark blue electrochromic film produced by oxidation electropolymerization of a triphenylamine derivative with an enhanced electron-withdrawing group

European Polymer Journal (2021)

Qiaozhen Pi Lijun Li Dongfang Qiu Hongwei Wang Xinfeng Cheng

Triphenylamine

Terpyridine

Prussian blue

10.1016/j.eurpolymj.2021.110684

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Citations (5)

((2-Hydroxynapthalen-1-yl)methylene)aniline derived Schiff base adducts of MTO: Synthesis and catalytic application

Journal of Organometallic Chemistry (2008)

A. Capape Mingdong Zhou Shuliang Zang Fritz E. Kühn

Methylene

Acceptor

Base (topology)

10.1016/j.jorganchem.2008.07.015

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Citations (26)

Adduct Formation of Dichloridodioxidomolybdenum(VI) and Methyltrioxidorhenium(VII) with a Series of Bidentate Nitrogen Donor Ligands

European Journal of Inorganic Chemistry (2009)

Ahmad M. Al‐Ajlouni Alev Günyar Mingdong Zhou Paul N. W. Baxter Fritz E. Kühn

Abstract The stability of a variety of bidentate N‐base adducts of MoO 2 Cl 2 and (CH 3 )ReO 3 (MTO) was investigated in thf and CH 2 Cl 2 as solvents. The formation constants were determined from the spectrophotometric data based on 1:1 adduct formation. The adduct formation constants for [MoO 2 Cl 2 L 2 ] (L 2 = bidentate nitrogen ligand) are 10 4 –10 6 times higher than those for [(CH 3 )ReO 3 L 2 ] with the same ligands under the same conditions. The adduct stability of both systems is very sensitive to the electronic nature of the ligands and increases with their donor ability. Hammett correlations of the formation constants against σ give relatively large negative values for the reaction constants ( ρ Re = –5.9, ρ Mo = –6.6). The stability is also governed by steric and strain factors. Thus, sterically hindered 6,6′‐disubstituted‐2,2′‐bipyridines do not form adducts with MTO, and only 6,6′‐dimethyl‐ and 6,6′‐diphenyl‐2,2′‐bipyridines form adducts with MoO 2 Cl 2 . However, these adducts are much less stable than other methyl derivatives of 2,2′‐bipridine adducts. The steric strain between the two methyl groups in 3,3‐dimethyl‐2,2′‐bipyridine influences the bipyridine planarity upon complexation and reduces the adduct stability. The thermodynamic parameters (enthalpy and entropy) were determined from temperature‐dependence studies. The adduct stability is mainly due to the strongly exothermic binding of the nitrogen‐bidentate ligand. The entropy change is small and has little effect on adduct stability.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

10.1002/ejic.200801103

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Citations (19)

CCDC 1949635: Experimental Crystal Structure Determination

The Cambridge Structural Database (2022)

Jinghao Zhang Yang Chen Jing Sun Jingyun Wang Mingdong Zhou

10.5517/ccdc.csd.cc23frgs

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Zincophilic MOF with N-functional groups for interfacial modification of stable aqueous zinc metal anodes

Journal of Materials Chemistry C (2024)

Na Sun Han Yu Xuedong Zhou Xiuwen Si Pengfei Wang

Rechargeable aqueous batteries using zinc as anode have attracted more and more attention. However, the uncontrolled dendrite growth and hydrogen evolution reaction seriously hinder the performance of zinc anode. In...

Surface Modification

10.1039/d4tc02883j

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CCDC 1435059: Experimental Crystal Structure Determination

The Cambridge Structural Database (2016)

Mengmeng Zuo Mingdong Zhou Dianwen Hu Fan Gao Sijie Dong

10.5517/cc1k5978

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Citations (0)