An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
By adopting a mixed-ligand strategy, three ZnII coordination polymers were prepared by hydrothermal reactions of zinc(ii) acetate with flexible 1,2-phenylenediacetic acid (H2phda) combining with three nitrogen-rich tectons namely, [Zn2(phda)2(bpo)2]n·2H2O (1), [Zn(phda)(pytz)]n (2), and [Zn(phda)(bib)]n·H2O (3) (where bpo = 2,5-bis(4-pyridyl)-1,3,4-oxadiazole, pytz = 3,5-di(4-pyridyl)-1,2,4-triazole, and bib = 1,4-bis(imidazol-1-yl)benzene). The single-crystal X-ray diffraction patterns reveal that the three compounds contain metal(ii)-carboxylate chains further extended by such nitrogen-rich co-ligands to afford a vast diversity of structures from two-dimensional (2D) stepwise grids (1), 2D double layers (2), to three-dimensional (3D)→3D 4-fold interpenetrating diamondoid networks. Furthermore, the structural differences in these complexes are primarily affected by the introduction of N-donor ancillary co-ligands so that their solid-state photoluminescence properties exhibit various emission spectra. Especially, compound 3 shows a guest-sensitive luminescence behaviour, which may be useful in applications as guest sensors.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
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