An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
Abstract Polymer electrolytes‐based lithium metal batteries have attracted much more attention for next‐generation energy storage devices owing to their high energy density and superior safety characteristics. However, there are still some obstacles to ameliorate interfacial compatibility between conventional polymer electrolytes with lithium metal anode and high‐voltage cathodes. It is noted that poly (maleic anhydride) copolymers (PMAC)‐based polymer electrolytes (PEs) exhibit superior interfacial compatibility with both lithium metal anode and high‐voltage cathodes in virtue of their distinctive structure. These superb characteristics will endow PMAC‐based PEs very promising candidate to develop highly safe and high‐energy‐density lithium metal batteries. So far, PMAC‐based PEs have been widely used in lithium metal batteries and high‐voltage lithium metal batteries because of their prominent advantages. Herein, recent key advances of PMAC‐based PEs are summarized. The key factors affecting ionic conductivity are elaborated in terms of structural control of PMAC, lithium salts, fillers, and plasticizers. Moreover, the interfacial compatibility of PMAC‐based PEs with lithium metal anode and high‐voltage cathodes is also discussed in details. Furthermore, potential challenges and prospects of PMAC‐based PEs are also envisioned at the end of this review. It is believed that this review will shed light on highly safe and high‐energy‐density lithium metal batteries.
From five to infinity: The pentameric cluster-based supramolecular units {[Mn(L)]4[Nb6Cl12(CN)6]} (H2L=7-Me-salen) can be extended into two 1D coordination polymers through either the formation of manganese dimers or through ditopic ligands (see picture). In 1 the supramolecular units are linked through phenoxo bridges between the Mn complexes, while in 2 a trans-1,2-bis(4-pyridyl)ethylene ligand connects the pentameric assemblies. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z604268_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
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