A novel flame retardant, zinc hydroxystannate-decorated graphene oxide (ZHS/GO) nanohybrid, was successfully prepared and well characterized. Herein, the ZHS nanoparticles could not only enhance the flame retardancy of GO with the synergistic flame-retardant effect of ZHS but also prevent the restack of GO to improve the mechanical properties of poly (vinyl chloride) (PVC) matrix. The structure characterization showed ZHS nanoparticles were bonded onto the surface of GO nanosheets and the ZHS nanoparticles were well distributed on the surface of GO. Subsequently, resulting ZHS/GO was introduced into flexible PVC and fire hazards and mechanical properties of PVC nanocomposites were investigated. Compared to neat PVC, thermogravimetric analysis exhibited that the addition of ZHS/GO into PVC matrix led to an improvement of the charring amount and thermal stability of char residue. Moreover, the incorporation of 5 wt.% ZHS/GO imparted excellent flame retardancy to flexible PVC, as shown by increased limiting oxygen index, reduced peak heat release rate, and total heat release tested by an oxygen index meter and a cone calorimeter, respectively. In addition, the addition of ZHS/GO nanohybrids decreased the smoke products and increased the tensile strength of PVC. Above-excellent flame-retardant properties are generally attributed to the synergistic effect of GO and ZHS, containing good dispersion of ZHS/GO in PVC matrix, the physical barrier of GO, and the catalytic char function of ZHS.
Nanoparticles as lubricant additives demonstrate powerful friction reduction and antiwear properties and are potential alternatives to traditional additives in line with green and environmentally friendly requirements. However, the vast majority of currently available research focuses on the tribological properties of various nanoparticles in base oils at laboratory, which has a large gap with their application in engineering. To cope with the rapid economic and industrial development in China, there is a need to improve the tribological properties of nanoparticles. This paper highlights the current status and development trend of nanoparticles as lubricant additives in China. The factors influencing the tribological properties of nanoparticles, such as their composition, particle size and morphology, as well as the base stocks and their combination with other additives, are summarized. Furthermore, the research progress in the lubrication mechanism of nanoparticles is discussed, and the issues concerning the application of nanoparticles as lubricant additives as well as their future directions are discussed. This review is expected to provide an impetus to guide the design of high-performance, fully formulated lubricant systems containing nanoparticles as the lubricant additive.
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