Aim of the study: evaluate and compare shear bond strength of MTA and Bio-Dentin to dentin after one day.Materials and Methods: Thirty upper premolars were selected and sectioned1 mm above the level of pulp horns to expose much dentin, specimens were randomly assigned into three groups, n=10 each.MTA, Bio-Dentin and calcium hydroxide (control) were mixed then filled in tubes [diameter & height = 3mm] then applied on dentin surfaces.After one day, the shear bond strength was tested using a universal testing device.A Stereo microscope was used to assess failure modes.Results: After one day, setting of these capping materials, shear bond strength of MTA and Bio-Dentin were significantly different from that of calcium hydroxide.However, shear bond strength of MTA and Bio-Dentin were not significantly different.Calcium hydroxide showed 100% adhesive failure, Bio-Dentin showed 12% mixed failure while MTA showed 15% mixed failure. Conclusion:After one day setting, MTA and Bio-Dentin showed shear bond strength higher than that of Calcium Hydroxide with some precedence to Bio-Dentin.
TiO 2 thin films have been deposited by several different sputtering processes: (i) dc magnetron sputtering (dcMS) employing various geometrical conditions, (ii) ion-assisted dc magnetron sputtering where additional ion bombardment of the growing films was performed with an auxiliary ECR ion source and (iii) high power impulse magnetron sputtering (HiPIMS). Films have been investigated mainly by grazing incidence x-ray diffraction and atomic force microscopy. It is shown that the highly energetic oxygen ions inherent in reactive sputtering of metal oxides are the dominant energetic species governing structure formation of TiO 2 films by their kinetic impact. The trajectories of these energetic oxygen ions strongly depend on the shape of the erosion trace and hence on the age of the target, which therefore has a strong influence on structure formation. Furthermore, in a HiPIMS discharge the role of this energetic oxygen ion bombardment is strongly intensified due to the increased target voltage and the lower deposition rate compared with a dcMS discharge. It is also demonstrated that films with pure rutile structure which are stable under a post-deposition thermal treatment can be deposited under intense energetic ion bombardment at low temperatures either by HiPIMS at high peak power densities or by ion-assisted dcMS.
Aim: to access the success rate of inferior alveolar nerve block (IANB) with 4% articaine (1/100000 epinephrine) containing 1% magnesium sulphate (MgSO4) in cases suffering from acute irreversible pulpitis (AIP) related to mandibular molars.Subjects & methods: 50 patients suffering from (AIP) were carefully selected, then divided into two groups, the first one (control) injected with 1.8 ml articaine (1/100000 epinephrine) by IANB while the second group (Test) injected with 1.8 ml articaine (1/100000 epinephrine -1% MgSO4).Lip numbness was considered a check for anesthetic success within 15 minutes.During the access cavity preparation and initial files placement, the pain scores were recorded according to Heft Parker Visual Analog Scale HP-VAS, Success was defined as the ability to access and instrument the tooth without pain (visual analogue scale rating of 0) or mild pain (visual analogue scale rating less than or equal to 54 mm).Then all data were analyzed by Chi-Square and T-Test, comparisons were considered significant if P < .05.Results: the success of the test group (MgSO4 group) was 85% while it was 55% for the control one.Conclusion: mixing 4% articaine (1/100000 epinephrine) with 1% MgSO4 had a positive effect on IANB success in patients with (AIP) related to the mandibular molars.
Using micro-computed tomography for assessment, this study examined the retreatability of filling materials from canals filled with Total Fill bioceramic sealer (FKG Dentaire, La Chaux de Fonds, Switzerland) and Dia-ProSeal epoxy resin-based sealer (Dia dent, Korea) sealing a guttapercha core.According to the sealer utilized, 30 mandibular premolars were randomly allocated into two groups.Canals were retreated two weeks following obturation using Fanta retreatment kit (FANTA dental materials, China).The length of time required for retreatment was listed.After obturation, retreatment and irrigant activation (XP endo finisher R), the roots were scanned.The Wilcoxon & Mann-Whitney tests were used to assess the data.In comparison to canals filled with Dia-ProSeal, Total Fill bioceramic sealer canals showed considerably less residual filling material (P< 0.05).The remaining material in both groups significantly decreased with irrigant activation (P< 0.05).The Dia-ProSeal group was found to have considerably less retreatment time than Total Fill bioceramic sealer group (P< 0.05).
Ni, Co, and Co–Ni bimetallic catalysts supported over SBA-15 and over SBA-15 doped with Zn or Ce oxides were prepared and tested in a methane dry reforming reaction. The loading of the metals in the catalyst was 5 wt % for either mono or bimetallic catalysts. The prepared catalysts were tested in a continuous-flow fixed-bed reactor at 800 °C under atmospheric pressure. XRD, TPR, TPD, and SEM characterization techniques were employed to investigate the catalytic properties of fresh catalysts. SEM and TGA were used to study the catalytic properties of spent catalysts. A remarkable effect on the reduction properties and catalytic performance of catalysts was observed after adding Zn and Ce. Over an 8 h test, Ni/SBA-15 showed the best activity and stability. The conversion was 90% for CH4 and CO2. Co–Ni/SBA-15 and Co–Ni/Ce–SBA-15 have shown a reasonable activity and stability. Selectivity of the Ni/SBA-15 catalyst was higher than all other catalysts as indicated by the H2/CO ratio. Co/SBA-15 and Co–Ni/Zn–SBA-15 showed a low activity and selectivity. TPD–NH3 profiles indicated that doping SBA-15 with Ce and/or Zn increased the catalyst acidic sites. Ni/SBA-15 is an excellent potential catalyst for commercial methane dry reforming processes.
In this paper, Polyolefin fibre which is produced from simple olefin (CnH2n) was mixed with dry sand to investigate the shear strength improvement of the admixture.Specimens with 0.5%, 1%, 1.5% and 2% fibre contents with yarns lengths of 15 mm and 30 mm are prepared in repeatable steps and tested in direct shear tests.Bearing capacity of hypothetical footing resting on ground surface of the tested fibre-reinforcedsand was estimated using Terzaghi's bearing capacity equation.Moreover, a parametric study includes thickness of reinforced layer, depth of foundation, and fibres content percent is conducted.In the parametric study, the continuous footing was analysed using procedures estimating the bearing capacity of layered soils.Results of shear strength tests indicated that, the inclusion of randomly distributed discrete fibres significantly improved the shear strength of sand.The optimum fibre percentage for improving both friction angle was about 1%.Adding fibre more than this ratio resulted in a significant reduction in soil shear strength parameters.The effect of fibre on sand apparent tensile cohesion is more pronounced compared to its effect on the friction angle.The parametric study indicates that having a continuous footing resting on a soil layer reinforced with 30 mm artificial fibres at 0.5% content provides the highest ultimate bearing capacity.Finally, the thickness of the reinforced layer and the depth of the foundation are among the parameters that affect bearing capacity.