Ze‐Ran Jing

Lanzhou University

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Yong‐Qiang Tu

Shanghai Jiao Tong University

Fu‐Min Zhang

Zhejiang Normal University

Shao-Hua Wang

General Research Institute for Nonferrous Metals (China)

Dao‐Yong Zhu

Lanzhou University

Fu‐Min Zhang

Lanzhou University

Xiao‐Ming Zhang

Lanzhou University

Bin‐Miao Yang

National University of Singapore

Meng Peng

Lanzhou University

Yunpeng Wang

Sichuan University

Qilong Chen

Xi'an University of Science and Technology

Cooperative Institutions

Lanzhou University

Lanzhou City University

Shanghai Jiao Tong University

Chinese Academy of Sciences

Collaborative Innovation Center of Chemical Science and Engineering Tianjin

Sichuan University

Xi'an University of Technology

Beijing University of Chemical Technology

Beihang University

Yunnan University

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CCDC 979259: Experimental Crystal Structure Determination

The Cambridge Structural Database (2015)

Jin-Bao Peng Yue Qi Ze‐Ran Jing Shao-Hua Wang Yong‐Qiang Tu

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cc11w00y

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CCDC 979257: Experimental Crystal Structure Determination

The Cambridge Structural Database (2015)

Jin-Bao Peng Yue Qi Ze‐Ran Jing Shao-Hua Wang Yong‐Qiang Tu

Crystal (programming language)

10.5517/cc11vzyt

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CCDC 2048013: Experimental Crystal Structure Determination

The Cambridge Structural Database (2021)

Ze‐Ran Jing Dong‐Dong Liang Jin‐Miao Tian Fu‐Min Zhang Yong‐Qiang Tu

10.5517/ccdc.csd.cc26r3y1

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Construction of the [6,5,7,5] Tetracyclic Core of Calyciphylline A Type Alkaloids via a Tandem Semipinacol Rearrangement/Nicholas Reaction

Organic Letters (2017)

Hui Shao Wen Bao Ze‐Ran Jing Yunpeng Wang Fu‐Min Zhang

A novel and efficient approach toward the assembly of the synthetically challenging tetracyclic [6,5,7,5] core structure of calyciphylline A-type alkaloids is developed. The synthetic route features a tandem semipinacol rearrangement/Nicholas reaction that has been devised strategically to construct the spirocyclic A/B ring and the sterically congested vicinal all-carbon quaternary carbon centers in high diastereoselectivity. Late-stage installation of the hydropyrrole ring and the strained 7-membered ring via a double-reductive amination and ring-closing metathesis, respectively, has also been realized.

Tandem

Vicinal

Ring-Closing Metathesis

Salt metathesis reaction

Quaternary carbon

Reductive amination

Cascade reaction

10.1021/acs.orglett.7b02274

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Citations (55)

CCDC 1983099: Experimental Crystal Structure Determination

The Cambridge Structural Database (2022)

Z. B. Yan Kun Dai Bin‐Miao Yang Zihao Li Yong‐Qiang Tu

10.5517/ccdc.csd.cc24kky7

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Efficient Oxa-Diels–Alder/Semipinacol Rearrangement/Aldol Cascade Reaction: Short Approach to Polycyclic Architectures

Organic Letters (2015)

Jin‐Bao Peng Qi Yue Ze‐Ran Jing Shao‐Hua Wang Yong‐Qiang Tu

A novel carbon electrophile induced intermolecular oxa-Diels-Alder/semipinacol rearrangement/aldol cascade reaction of allylic silyl ether with β,γ-unsaturated α-ketoester has been developed under the promotion of SnCl4. This highly efficient transformation enables the quick construction of polycyclic architectures with up to five contiguous stereogenic centers in a single operation with moderate to good yields as well as high diastereoselectivity and would provide versatile short approaches to frameworks and/or analogues of numerous biologically important polycyclic natural products.

Stereocenter

Aldol reaction

10.1021/acs.orglett.5b00125

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ChemInform Abstract: Efficient Oxa‐Diels—Alder/Semipinacol Rearrangement/Aldol Cascade Reaction: Short Approach to Polycyclic Architectures.

ChemInform (2015)

Jin‐Bao Peng Qi Yue Ze‐Ran Jing Shao‐Hua Wang Yong‐Qiang Tu

Abstract A novel carbon electrophile induced intermolecular oxa‐Diels—Alder/semipinacol rearrangement/aldol cascade reaction of allylic silyl ether with β,γ‐unsaturated α‐ketoester is developed under the promotion of SnCl 4 .

Aldol reaction

Silyl ether

10.1002/chin.201528066

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CCDC 1983097: Experimental Crystal Structure Determination

The Cambridge Structural Database (2022)

Z. B. Yan Kun Dai Bin‐Miao Yang Zihao Li Yong‐Qiang Tu

10.5517/ccdc.csd.cc24kkw5

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Enantioselective Construction of 2-Aryl-2,3-dihydrobenzofuran Scaffolds Using Cu/SPDO-Catalyzed [3 + 2] Cycloaddition

Organic Letters (2021)

Ze‐Ran Jing Dong‐Dong Liang Jin‐Miao Tian Fu‐Min Zhang Yong‐Qiang Tu

A new, efficient approach toward the preparation of 2-aryl-2,3-dihydrobenzofuran scaffolds through the Cu/SPDO-catalyzed [3 + 2] cycloaddition between quinone ester and styrene derivatives has been developed. The procedure features excellent enantioselectivities (up to 99% ee), high yields (up to 96%), and broad substrate tolerance. Additionally, asymmetric synthesis of natural corsifurans A and B from commercially available starting materials has also been achieved in two or three steps using this reaction as a key transformation.

10.1021/acs.orglett.0c04241

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Citations (44)

CCDC 1559292: Experimental Crystal Structure Determination

The Cambridge Structural Database (2017)

Hui Shao Wen Bao Ze‐Ran Jing Yunpeng Wang Fu‐Min Zhang

10.5517/ccdc.csd.cc1pbkrb

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