Vincent Terrasson

Université de Technologie de Compiègne

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Damien Prim

Centre National de la Recherche Scientifique

Clara Viñas

Institut de Ciència de Materials de Barcelona

José Giner Planas

Institut de Ciència de Materials de Barcelona

Mark E. Light

University of Southampton

Erwann Guénin

Université de Technologie de Compiègne

Jérôme Marrot

Centre National de la Recherche Scientifique

A Gaucher

Institut Lavoisier de Versailles

Sylvain R. A. Marque

Aix-Marseille Université

Damien Prim

Institut Lavoisier de Versailles

M.B. Hursthouse

University of Southampton

Cooperative Institutions

Centre National de la Recherche Scientifique

Institut Lavoisier de Versailles

Sorbonne Université

Université de Technologie de Compiègne

Université de Versailles Saint-Quentin-en-Yvelines

École Supérieure de Chimie Organique et Minérale

Institut Charles Gerhardt Montpellier

École Nationale Supérieure de Chimie de Montpellier

Université Paris-Saclay

Aix-Marseille Université

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Intermolecular FeCl₃‐Catalyzed Hydroamination of Styrenes.

ChemInform (2007)

Julien Michaux Vincent Terrasson Sylvain R. A. Marque Johny Wehbe Damien Prim

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Hydroamination

10.1002/chin.200737075

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CCDC 758189: Experimental Crystal Structure Determination

The Cambridge Structural Database (2010)

Vincent Terrasson A. Van Der Lee R.M. De Figueiredo J.‐M. Campagne

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cctfyqw

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Mechanosynthesis and Polymerization of Biosourced Styrene Derivatives Based on Building Blocks of Lignin

ACS Sustainable Chemistry & Engineering (2024)

Joanna Michalska‐Walkowiak Elânia Sn Antonio Fanny Coumes Jutta Rieger Vincent Terrasson

Finding and developing new biosourced materials that can compete with the current petro-sourced ones are a top priority in order to transition to a more sustainable society. Although the preparation of biosourced polyesters or polyamides is quite well described, finding biosourced and sustainable alternatives to petro-sourced polystyrene is still challenging. Herein, we report the synthesis of polystyrenes prepared in three steps from vanillin, 4-hydrobenzaldehyde, and syringaldehyde, compounds that can be obtained through lignin depolymerization under oxidative conditions. The synthesis involves the conversion of these biosourced platforms into polymerizable styrene derivatives through a methylation of the hydroxyl group followed by an olefination of the aldehyde function. The monomers were first synthesized under conventional conditions using solvents. Then, the synthesis was improved from the sustainability point of view by using a ball mill under solventless conditions, generating much less waste in the process. The three monomers were then converted into biosourced homopolymers through free radical polymerization in bulk, providing functional polystyrene derivatives with thermal properties comparable to those of common petro-sourced polystyrene.

Polystyrene

Depolymerization

Syringaldehyde

10.1021/acssuschemeng.3c06050

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CCDC 756376: Experimental Crystal Structure Determination

The Cambridge Structural Database (2011)

Vincent Terrasson Y. Garcia Pau Farràs Francesç Teixidor Clara Viñas

10.5517/cctd27h

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Organic Nanoparticles as Anticancer and Theranostic Devices

HAL (Le Centre pour la Communication Scientifique Directe) (2014)

Vincent Terrasson Myriam Roy Florian Corréard Marie‐Anne Estève Diane Braguer

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Synthèse de diarylméthylamines

HAL (Le Centre pour la Communication Scientifique Directe) (2006)

Vincent Terrasson Sylvain R. A. Marque Damien Prim

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CCDC 769336: Experimental Crystal Structure Determination

The Cambridge Structural Database (2016)

Grégory Pieters Vincent Terrasson A Gaucher Damien Prim Jérôme Marrot

10.5517/ccdc.csd.ccttk9g

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Synthesis and Molecular Structure of Symmetrical 1,8‐Diarylnaphthalenes

European Journal of Organic Chemistry (2010)

Grégory Pieters Vincent Terrasson A Gaucher Damien Prim Jérôme Marrot

Abstract The synthesis of substituted 1,8‐diarylnaphthalenes is reported. A bis‐Suzuki coupling strategy starting from 1,8‐dibromonaphthalene provides a useful and general route to the 1,8‐diarylnaphthalene scaffold. In this context, N‐heterocyclic benzhydrylamine ligands, in combination with PdCl 2 , were found to form especially efficient catalytic systems. The syn / anti ratios were determined in solution from their 1 H NMR spectra. Analysis of the molecular structure in the solid state for six new targets focused on deformation of the naphthalene core. The observed lack of planarity occurs as a result of several parameters, such as the nature and number of substituents, the substitution pattern as well as steric congestion and π‐stacking between cofacial rings.

Planarity testing

Suzuki reaction

10.1002/ejoc.201000685

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Citations (19)

Vers une synthèse plus verte de matériaux pour l’électronique organique par l’utilisation de nanocatalyseurs

HAL (Le Centre pour la Communication Scientifique Directe) (2021)

Mekki Negui Erwann Guénin Frédéric Sauvage Victorien Jeux Vincent Terrasson

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Applications of Lignin in Energy Conversion: Solar Cells, Fuel Cells and Photocatalysis

CRC Press eBooks (2022)

Zhao Zhang Mekki Negui Erwann Guénin Vincent Terrasson Victorien Jeux

As the need to produce more sustainably and fight climate change is becoming a primordial and urgent research interest, energy conversion, which consists in transforming some renewable energy source like light or biomass to electricity or chemical energy, has attracted a lot of attention. Indeed, the different processes involving energy conversion could provide some interesting solutions in the effort to be less dependent on fossil fuel and to consider the environmental impact. Nanomaterials and nanocomposites derived from lignin have found more and more applications in energy-conversion processes and devices. As a cheap and abundant biopolymer, lignin and its derivatives could offer greener alternatives to some of the materials currently used. This chapter will focus on three different aspects of energy conversion: solar cells, fuels cells, and photocatalysis. In photovoltaic devices, lignin nanomaterials have been employed as absorber, electrolyte, in the preparation of electrodes or hole-transporting materials. In fuel cells, lignin could directly act as fuel to produce electricity, but it could also help improving the properties of membranes and electrodes through incorporation of its nanoderivatives. In photocatalysis, nanolignin, and other nanomaterials prepared from it, have essentially been used as support for the metallic catalysts.

Solar fuel

Energy transformation

10.1201/9781003245261-9

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