Abstract Die anodische Oxidation verdünnter Cu(Hg)‐Poolelektroden (maximaler Molenbruch des Cu: 0.031) in wäßrige Lösungen von Na 3 PO 4 und NaOH (pH‐Bereich l0.5‐12.2) bewirkt eine Reihe von Potential‐Zeit‐Transienten entsprechend der Bildung von Cu 2 O, CuO und Cu(OH) 2 beim höheren pH‐Wert und von Cu 2 O sowie 2 löslichen Spezies (wahrscheinlich CuO 2‐ und HCuO2 ‐ ) beim niedrigeren pH‐Wert.
Abstract It is shown that the tetranuclear Cu complexes (I) can be sequentially or simultaneously transmetalated with the mer‐Co complex (II) and different bis(S‐methylisopropylidenehydrazinecarbodithioato)metal(II) reagents in stoichiometric reactions to give the dimeric products (IV) that are predictable a) from (II) as the fastest transmetalator for (I) giving (III) and for (III), and b) from the stability decrease for the M(NS) 2 reagents in the order M: Cu > Ni > Co > Zn.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProducts and kinetics of the oxidation of neutral dimeric iodo(N,N,N'N'-tetraalkyl diamine)copper(I) complexes [LCuI]2 by dioxygen in nitrobenzeneMohamed A. El-Sayed, Geoffrey Davies, and Taher S. KasemCite this: Inorg. Chem. 1990, 29, 23, 4730–4735Publication Date (Print):November 1, 1990Publication History Published online1 May 2002Published inissue 1 November 1990https://pubs.acs.org/doi/10.1021/ic00348a029https://doi.org/10.1021/ic00348a029research-articleACS PublicationsRequest reuse permissionsArticle Views167Altmetric-Citations18LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelective transmetalation and demetalation of heteropolynuclear metal complexesGeoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, Maher Henary, Taher S. Kasem, and Colleen A. MartinCite this: Inorg. Chem. 1986, 25, 22, 3904–3909Publication Date (Print):October 1, 1986Publication History Published online1 May 2002Published inissue 1 October 1986https://pubs.acs.org/doi/10.1021/ic00242a016https://doi.org/10.1021/ic00242a016research-articleACS PublicationsRequest reuse permissionsArticle Views56Altmetric-Citations18LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts