Chen‐Liang Deng

Zhejiang University of Water Resource and Electric Power

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Xing‐Guo Zhang

Wenzhou University

Jin‐Heng Li

Henan Normal University

Ri‐Yuan Tang

South China Agricultural University

Ye‐Xiang Xie

Nanchang Hangkong University

Bo‐Lun Hu

Institute of Theoretical Physics

Ren‐Jie Song

Nanchang Hangkong University

Bo Yao

Beijing Institute of Technology

Lei‐Lei Sun

Shanghai Electric (China)

Peng‐Cheng Qian

Wenzhou University

Wenying Wang

Kunming Medical University

Cooperative Institutions

Wenzhou University

Chinese Academy of Sciences

Hunan University

Central South University

Hunan Normal University

Guangzhou Research Institute of Non-ferrous Metals

East China University of Science and Technology

Shanghai Jiao Tong University

Soochow University

University of Chinese Academy of Sciences

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ChemInform Abstract: Copper‐Mediated Stereospecific C—H Oxidative Sulfenylation of Terminal Alkenes with Disulfides.

ChemInform (2016)

Hai‐Yong Tu Bo‐Lun Hu Chen‐Liang Deng Xing‐Guo Zhang

Abstract A variety of terminal alkenes (I) and (IV) undergo oxidative coupling reaction with various diaryl disulfides (II) to afford the corresponding (E)‐vinyl sulfides in moderate to good yields.

Stereospecificity

10.1002/chin.201608092

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ChemInform Abstract: FeBr₃‐Catalyzed Tandem Reaction of N‐Propargylamides with Disulfides or Diselenides for the Synthesis of Oxazole Derivatives.

ChemInform (2016)

Xu‐Hong Gao Peng‐Cheng Qian Xing‐Guo Zhang Chen‐Liang Deng

Zhàng

10.1002/chin.201635109

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Iron‐Facilitated Iodine‐Mediated Electrophilic Annulation of N,N‐Dimethyl‐2‐alkynylanilines with Disulfides or Diselenides

Advanced Synthesis & Catalysis (2011)

Hui‐Ai Du Ri‐Yuan Tang Chen‐Liang Deng Yan Liu Jin‐Heng Li

Abstract An efficient synthesis of N ‐methyl‐3‐chalcogeno‐indoles has been developed via iodine‐mediated electrophilic annulation reactions of 2‐alkynylaniline derivatives with disulfides or diselenides. In the presence of iodine and iron, a variety of 2‐alkynylanilines selectively underwent the electrophilic annulation with numerous disulfides or diselenides leading to the corresponding 3‐sulfenylindoles and 3‐selenenylindoles in moderate to excellent yields. It is noteworthy that iron can promote the reaction.

Annulation

10.1002/adsc.201100349

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Citations (137)

Mild and Ligand‐Free Palladium‐Catalyzed Cross‐Couplings between Aryl Halides and Arylboronic Acids for the Synthesis of Biaryls and Heterocycle‐Containing Biaryls

European Journal of Organic Chemistry (2007)

Chen‐Liang Deng Shengmei Guo Ye‐Xiang Xie Jin‐Heng Li

Abstract Ligand‐free palladium‐catalyzed Suzuki–Miyaura cross‐couplings between aryl halides and arylboronic acids performed at room temperature are presented. It was found that both solvent and base had a fundamental influence on the reaction, and the most effective system in terms of yield and rate was observed to be the combination of Pd(OAc) 2 with MeONa and alcohols. In the presence of Pd(OAc) 2 and MeONa, a variety of aryl halides reacted very rapidly with arylboronic acids in good to excellent yields at room temperature in EtOH as the solvent. Moreover, the Pd(OAc) 2 /MeONa catalytic system could also be applied in couplings between heteroaryl halides and arylboronic acids to provide satisfactory results in MeOH as the solvent after prolonged reaction times. It is noteworthy that the reactions were conducted under mild, aerobic, and ligand‐free conditions.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

Aryl halide

10.1002/ejoc.200600879

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Citations (62)

ChemInform Abstract: Synthesis of 3‐Trifluoromethylbenzofurans via Palladium‐Catalyzed Tandem Elimination/Annulation of β‐Chloro‐β‐(trifluoromethyl)styrenes with 2‐Halophenols.

ChemInform (2014)

Chong Wang Lianhui Chen Chen‐Liang Deng Xing‐Guo Zhang

Alma mater

Zhàng

Annulation

10.1002/chin.201429127

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NH₄PF₆-promoted cyclodehydration of α-amino carbonyl compounds: efficient synthesis of pyrrolo[3,2,1-ij]quinoline and indole derivatives

RSC Advances (2014)

Xiaoming Ji Shu‐Juan Zhou Chen‐Liang Deng Fan Chen Ri‐Yuan Tang

NH₄PF₆is an inexpensive, safe, and low-toxicity inorganic salt; it was found to promote the cyclodehydration of α-amino carbonyl compounds in the absence of metal reagents.

Quinoline

10.1039/c4ra11168k

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Citations (9)

Iron-Catalyzed Benzylation Reaction of Arenes with Benzyl Thiocyanates

Synlett (2012)

Jin‐Heng Li Ri‐Yuan Tang Xiaokang Guo Dongyun Zhao Xing‐Guo Zhang

A novel, regioselective protocol for the synthesis of diphenylmethane derivatives has been developed by using iron-catalyzed Friedel-Crafts reaction of arenes with benzyl thiocyanates. In the presence of FeBr3, a variety of benzyl thiocyanates underwent the reaction with arenes to selectively afford the corresponding diarylmethane derivatives in moderate to high yields.

Diphenylmethane

Friedel–Crafts reaction

Reaction conditions

10.1055/s-0031-1290343

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Citations (2)

Palladium-Catalyzed Methylsulfonylation of Alkyl Halides Using Dimethyl Sulfite as SO₂ Surrogate and Methyl Source

The Journal of Organic Chemistry (2021)

Yanhua Xin Ying-Qiong Guo Xing‐Guo Zhang Chen‐Liang Deng

A novel and efficient method for the synthesis of methyl sulfone derivatives via palladium-catalyzed methylsulfonylation of alkyl halides with dimethyl sulfite has been described. A variety of aryl and alkyl iodides underwent the sulfonylation smoothly to furnish methyl sulfites in moderate to excellent yields.

Sulfone

10.1021/acs.joc.1c02188

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Citations (5)

ChemInform Abstract: Palladium‐Catalyzed Oxidative Carbamoylation of Isoquinoline N‐Oxides with Formylamides by Means of Dual C—H Oxidative Coupling.

ChemInform (2015)

Bo Yao Chen‐Liang Deng Yan Liu Ri‐Yuan Tang Xing‐Guo Zhang

Abstract The first examples for the carbamoylation of isoquinoline N‐oxides with formylamides furnishing isoquinoline‐1‐carboxamides such as (III) and (V) in moderate to good yields are given.

Isoquinoline

10.1002/chin.201529203

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Pd(OAc)₂/DABCO as an Inexpensive and Efficient Catalytic System for Hiyama Cross-Coupling Reactions of Aryl Halides with Aryltrimethoxysilanes

Synthesis (2005)

Jin‐Heng Li Chen‐Liang Deng Wenjie Liu Ye‐Xiang Xie

Pd(OAc)2/DABCO was found to be an inexpensive and efficient catalyst system for Hiyama cross-coupling reactions of aryl halides with aryltrimethoxysilanes. In the presence of Pd(OAc)2, DABCO, and TBAF, coupling of a number of aryl halides with aryltrimethoxysilanes underwent efficiently to afford the corresponding cross-coupled products in moderate to excellent yields.

DABCO

Coupling reaction

Aryl halide

10.1055/s-2005-918411

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Citations (39)