F. Rivals

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc6zvff

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(2S,4S,S_Fc)-2-[2-(Diphenylthiophosphinoyl)ferrocenyl]-4-methoxymethyl-1,3-dioxane

Acta Crystallographica Section C Crystal Structure Communications (2006)

Jean‐Claude Daran Éric Manoury Lucie Routaboul F. Rivals

The title compound, [Fe(C5H5)(C23H24O3PS)], is a very useful intermediate for the synthesis of enantiomerically pure (S)-2-[(diphenylthiophosphinoyl)ferrocenyl]methanol or (S)-2-(diphenylthiophosphinoyl)ferrocenecarboxaldehyde. The dioxane ring has a chair conformation and is twisted with respect to the cyclopentadienyl ring to which it is attached. There is an intermolecular C—H⋯O hydrogen-bonding interaction which links the molecules into C(8) chains developing parallel to the a axis. Owing to this weak interaction, the two cyclopentadienyl rings are twisted with respect to each other by 16.0 (3)°, and so have a conformation which might be regarded as intermediate between eclipsed and staggered. The absolute configuration deduced from the X-ray analysis fully confirms the sterochemistry expected from the chemical pathway.

Thio-

Eclipsed conformation

10.1107/s0108270106025662

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CCDC 199632: Experimental Crystal Structure Determination

The Cambridge Structural Database (2003)

J.F. Bickley Richard P. Bonar‐Law G.T. Lawson P.I. Richards F. Rivals

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc6pqrb

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CCDC 142616: Experimental Crystal Structure Determination

The Cambridge Structural Database (2000)

G.T. Lawson F. Rivals M. Tascher Cristina C. Jacob J.F. Bickley

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc4sdjt

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CCDC 975139: Experimental Crystal Structure Determination

The Cambridge Structural Database (2013)

F. Rivals G.T. Lawson M.A. Benson P.I. Richards Stefano Zacchini

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cc11qq3l

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CCDC 199625: Experimental Crystal Structure Determination

The Cambridge Structural Database (2003)

J.F. Bickley Richard P. Bonar‐Law G.T. Lawson P.I. Richards F. Rivals

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc6pqj3

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CCDC 152011: Experimental Crystal Structure Determination

The Cambridge Structural Database (2001)

F. Rivals Alexander Steiner

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cc535l0

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CCDC 191124: Experimental Crystal Structure Determination

The Cambridge Structural Database (2003)

F. Rivals Alexander Steiner

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/cc6dw9r

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CCDC 191121: Experimental Crystal Structure Determination

The Cambridge Structural Database (2003)

F. Rivals Alexander Steiner

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc6dw6n

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CCDC 191122: Experimental Crystal Structure Determination

The Cambridge Structural Database (2003)

F. Rivals Alexander Steiner

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

Crystal (programming language)

10.5517/cc6dw7p

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