The DIC (dissolved inorganic carbon) of interstitial waters from sediments of a small carbonate-precipitating lake in southern Ontario has highly enriched δ 13 C values of up to +13‰ relative to PDB (Peedee belemnite). This post-depositional isotopic enrichment is attributed to the metabolism of methanogenic bacteria. The δ 13 C values of marl in the sediment profile are also enriched by an average of +3 to +4‰ relative to the associated molluscs.Photosynthetically induced carbonate precipitation and post-depositional recrystallization are among the processes that are considered to contribute to the isotopically enriched marls. Evidence for the latter process is drawn from geochemical analyses on interstitial waters, which show them to be at or very close to saturation with respect to calcite, indicating that net calcite dissolution has occurred, probably under the influence of high pCO 2 's generated by methanogenic bacteria. Such freshwater carbonate sediments with interstitial waters enriched in 13 C provide a unique environment for study of isotope relations during carbonate diagenesis under accessible conditions and with a time scale of geologic relevance.
Holocene dolomite forms in the sediment of Lake Hayward, a small, permanent, hypersaline lake in the Clifton-Preston Lakeland System, Western Australia. The Clifton-Preston Lakeland System is similar in climate, geography, and sedimentology to the Coorong Region of South Australia. However, dolomite in Lake Hayward is not a primary precipitate as in the Coorong but is of diagenetic origin. The diagenetic origin can be deduced from the combination of the following criteria: (1) the dolomite occurs only between 60-70 cm from the sediment water interface; (2) dolomite occurs as luminescing cement; and (3) dolomite has pristine well-formed rhomb-shaped crystals. The source of magnesium for dolomitization is probably from the concentration of inflowing groundwater by evaporation and the selective removal of calcium by aragonite/calcite precipitation. Although the mechanisms of dolomite formation in Lake Hayward are slightly different than in the Coorong, the presence of Holocene dolomite in an almost identical setting illustrates the importance of the 'Coorong model' for dolomite formation in modern coastal areas.