Paride Grisenti

Bioseutica (Netherlands)

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Patrizia Ferraboschi

University of Milan

100

Enzo Santaniello

University of Milan

Samuele Ciceri

University of Milan

Ada Manzocchi

University of Milan

Fiorella Meneghetti

University of Milan

Silvana Casati

University of Milan

Alberto Fiecchi

Brunel University of London

Diego Colombo

University of Milan

Carlo Castellano

University of Milan

Matteo Mori

University of Milan

Cooperative Institutions

University of Milan

Mylan (South Africa)

Istituti di Ricovero e Cura a Carattere Scientifico

University of Cagliari

Mylan (Switzerland)

Università degli Studi del Piemonte Orientale “Amedeo Avogadro”

National Research Council

University of Pavia

Fondazione IRCCS Ca' Granda Ospedale Maggiore Policlinico

University of Perugia

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Polyethylene Glycols as Solvents for Anionic Activation: Synthesis of Thioacetates by Means of Potassium Thioacetate in Polyethylene Glycol 400

Synthetic Communications (1987)

Patrizia Ferraboschi Alberto Fiecchi Paride Grisenti Enzo Santaniello Susanna Trave

Abstract Recently, polyethylene glycols (PEGS) of various molecular weights have been proposed as solvent promoters for various reactions 1, 2. We wish to report on the use of PEG 400 as solvent for the anionic activation of potassium thioacetate, which could be used for the preparation of alkyl and benzyl thioacetates from the corresponding halides or alcohol derivatives. The method can be synthetically significant, since from thioacetates the corresponding thiols can be easily prepared under a variety of mild conditions 3.

Benzyl alcohol

10.1080/00397918708057787

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Citations (26)

ChemInform Abstract: Enantioselective Pseudomonas fluorescens (P. cepacia) Lipase‐Catalyzed Irreversible Transesterification of 2‐Methyl‐1,2‐diols in an Organic Solvent.

ChemInform (1995)

Patrizia Ferraboschi Silvana Casati Paride Grisenti Enzo Santaniello

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

Pseudomonas fluorescens

10.1002/chin.199515064

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Biohydrogenation of unsaturated compounds by Saccharomyces cerevisiae. Part 1. Stereochemical aspects of the reaction and preparation of useful bifunctional chiral synthons

Journal of the Chemical Society. Perkin transactions I/Journal of the Chemical Society. Perkin transactions. I (1987)

Patrizia Ferraboschi Paride Grisenti Rosangela Casati Alberto Fiecchi Enzo Santaniello

Ethyl 4,4-dimethoxy-3-methylbut-2-enoate, (1; R = CO2Et) has been prepared as a mixture of (E) and (Z)-isomers, the (E)/(Z) ratio depending on the base used. Each isomeric mixture of (1a) and (1b) has been used as substrate for biohydrogenation with fermenting Saccharomyces cerevisiae(baker's yeast) and the (Z)-isomer seems to be the preferred substrate. (E)-Unsaturated alcohols such as (3a) and (5d) are not reduced to the corresponding saturated hydroxy derivatives by baker's yeast. The (E)-aldehyde (3c) and its acetal (3d) are mainly reduced to the corresponding (E)-alcohol (3a),;the saturated hydroxy ester (2a) being formed to a minor extent, especially with (3d). In contrast, biohydrogenation is also successful with the (E)-isomers of compounds (3e), (3f), and (3b)(R2= alkyl or alkenyl). If the allylic oxygenated group to be reduced is not α-methyl substituted, reduction to the corresponding saturated alcohols readily occurs with the (E)-isomers as in the case of (5f). For this last biohydrogenation, the stereochemistry of the methyl-bearing, carbon has been established. by chemical correlations. The α,β-disubstituted allylic acetal (6a) is not biohydrogenated by the yeast, but a mixture of unsaturated hydroxy ester (6b) and γ-hydroxy lactone (8) is recovered from the incubation.

Synthon

10.1039/p19870001743

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Citations (27)

Further studies on sodium borohydride-polyethylene glycol 400 as a novel reducing system

The Journal of Organic Chemistry (1987)

Enzo Santaniello Patrizia Ferraboschi Alberto Fiecchi Paride Grisenti Ada Manzocchi

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFurther studies on sodium borohydride-polyethylene glycol 400 as a novel reducing systemEnzo Santaniello, Patrizia Ferraboschi, Alberto Fiecchi, Paride Grisenti, and Ada ManzocchiCite this: J. Org. Chem. 1987, 52, 4, 671–674Publication Date (Print):February 1, 1987Publication History Published online1 May 2002Published inissue 1 February 1987https://pubs.acs.org/doi/10.1021/jo00380a033https://doi.org/10.1021/jo00380a033research-articleACS PublicationsRequest reuse permissionsArticle Views424Altmetric-Citations13LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

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Sodium borohydride

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10.1021/jo00380a033

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Enzymic resolution of 2-substituted oxiranemethanols, a class of synthetically useful building blocks, bearing a chiral quaternary center

The Journal of Organic Chemistry (1991)

Patrizia Ferraboschi Daria Brembilla Paride Grisenti Enzo Santaniello

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEnzymic resolution of 2-substituted oxiranemethanols, a class of synthetically useful building blocks, bearing a chiral quaternary centerPatrizia Ferraboschi, Daria Brembilla, Paride Grisenti, and Enzo SantanielloCite this: J. Org. Chem. 1991, 56, 18, 5478–5480Publication Date (Print):August 1, 1991Publication History Published online1 May 2002Published inissue 1 August 1991https://pubs.acs.org/doi/10.1021/jo00018a057https://doi.org/10.1021/jo00018a057research-articleACS PublicationsRequest reuse permissionsArticle Views315Altmetric-Citations29LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

Center (category theory)

10.1021/jo00018a057

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Citations (33)

ChemInform Abstract: A Chemoenzymatic Approach to Enantiomerically Pure (R)- and (S)-2,3- Epoxy-2-(4-pentenyl)-propanol, a Chiral Building Block for the Synthesis of (R)- and (S)-Frontalin.

ChemInform (1993)

Patrizia Ferraboschi Silvana Casati Paride Grisenti Enzo Santaniello

10.1002/chin.199322280

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Antithrombotic Argatroban : crystallographic, spectroscopic and theoretical investigation on the efficiently resolved 21-(R) and 21-(S) diastereoisomers

Patrizia Ferraboschi Fiorella Meneghetti Laura Legnani Diego Colombo J. Perricci

Diastereomer

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The biocatalytic approach to the preparation of enantiomerically pure chiral building blocks

Chemical Reviews (1992)

Enzo Santaniello Patrizia Ferraboschi Paride Grisenti Ada Manzocchi

ADVERTISEMENT RETURN TO ISSUEPREVArticleThe biocatalytic approach to the preparation of enantiomerically pure chiral building blocksEnzo Santaniello, Patrizia Ferraboschi, Paride Grisenti, and Ada ManzocchiCite this: Chem. Rev. 1992, 92, 5, 1071–1140Publication Date (Print):July 1, 1992Publication History Published online1 May 2002Published inissue 1 July 1992https://doi.org/10.1021/cr00013a016Request reuse permissionsArticle Views2120Altmetric-Citations472LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (7 MB) Get e-Alertsclose Get e-Alerts

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10.1021/cr00013a016

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Citations (524)

CCDC 2248213: Experimental Crystal Structure Determination

The Cambridge Structural Database (2023)

Samuele Ciceri Diego Colombo Enrico Mario Alessandro Fassi Patrizia Ferraboschi Giovanni Grazioso

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccdc.csd.cc2fgg0d

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ChemInform Abstract: Biohydrogenation of Unsaturated Compounds by Saccharomyces cerevisiae. Part 2. (S)‐(‐)‐Ethyl 4‐Hydroxy‐3‐methylbutanoate as a Chiral Synthon for the Preparation of (25S)‐26‐Hydroxycholesterol.

ChemInform (1987)

Patrizia Ferraboschi Alberto Fiecchi Paride Grisenti Enzo Santaniello

Synthon

10.1002/chin.198748328

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