Rubina Jabeen

Chinese Academy of Sciences

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Nasir Ali

Zhejiang Lab

Li Qi

Chinese Academy of Sciences

Muhammad Ali Tajwar

Chinese Academy of Sciences

Dan Li

Jinan University

Changyan Cao

Chinese Academy of Sciences

Xiangru Zhang

Chinese Academy of Sciences

Dihua Shangguan

Chinese Academy of Sciences

Yutong Liu

Southwest Jiaotong University

Yutong Liu

Shanghai Jiao Tong University

Yutong Liu

Hohai University

Cooperative Institutions

Chinese Academy of Sciences

Beijing National Laboratory for Molecular Sciences

University of Chinese Academy of Sciences

Jinan University

North University of China

Institute of Chemistry

Center for Excellence in Education

Harbin Institute of Technology

East China University of Science and Technology

Wuhan Institute of Technology

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Confinement-Induced Biocatalytic Activity Enhancement of Light- and Thermoresponsive Polymer@Enzyme@MOF Composites

ACS Applied Materials & Interfaces (2024)

Rubina Jabeen Muhammad Ali Tajwar Changyan Cao Yutong Liu Shuqian Zhang

Metal-organic frameworks (MOFs) are favorable hosting materials for fixing enzymes to construct enzyme@MOF composites and to expand the applications of biocatalysts. However, the rigid structure of MOFs without tunable hollow voids and a confinement effect often limits their catalytic activities. Taking advantage of the smart soft polymers to overcome the limitation, herein, a protection protocol to encapsulate the enzyme in zeolitic imidazolate framework-8 (ZIF-8) was developed using a glutathione-sensitive liposome (L) as a soft template. Glucose oxidase (GOx) and horseradish peroxidase (HRP) were first anchored on a light- and thermoresponsive porous poly(styrene-maleic anhydride-

10.1021/acsami.4c05742

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Construction of Photo- and Thermo-Responsive Polymer-MOF@Enzyme Composites for Enhancing Its Biocatalytic Performance

Chemical Research in Chinese Universities (2024)

Muhammad Ali Tajwar Nasir Ali Xiangru Zhang Rubina Jabeen Yutong Liu

10.1007/s40242-024-4140-3

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Encapsulation of an enzyme-immobilized smart polymer membrane in a metal–organic framework for enhancement of catalytic performance

Journal of Materials Chemistry B (2024)

Rubina Jabeen Nasir Ali Muhammad Ali Tajwar Yutong Liu Dong Luo

Encapsulation of enzymes within porous materials has shown great promise for protecting enzymes from denaturation, increasing their tolerance to harsh environments and promoting their industrialization. However, controlling the conformational freedom of the encapsulated enzymes to enhance their catalytic performance remains a great challenge. To address this issue, herein, following immobilization of GOx and HRP on a thermo-responsive porous poly(styrene-maleic-anhydride-

Encapsulation

Maleic anhydride

10.1039/d4tb00162a

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