Leigh F. Jones

The dimeric complex [Mn(III)(2)(Naphth-sao)(2)(Naphth-saoH)(2)(MeOH)(2)]·4MeOH (1·4MeOH), acts as a simple model complex with which to examine the magneto-structural relationship in polymetallic, oxime-bridged Mn(III) complexes. Dc magnetic susceptibility studies reveal that ferromagnetic exchange is mediated through the heavily twisted Mn-O-N-Mn moiety (J = +1.24 cm(-1)) with magnetisation measurements at low temperatures and high fields suggesting significant anisotropy. Simulations of high field, high frequency EPR data reveal a single ion anisotropy, D((Mn(III))) = -3.94 cm(-1). Theoretical studies on simplified model complexes of 1 reveal that calculated values of the exchange coupling and the anisotropy are in excellent agreement with experiment, with the weak ferromagnetism resulting from an accidental orthogonality between the Mn-N-O plane of the first Mn(III) ion and the Jahn-Teller axis of the second Mn(III) ion.

Moiety

10.1039/c2dt30674c

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CCDC 682653: Experimental Crystal Structure Determination

The Cambridge Structural Database (2009)

G. Karotsis Leigh F. Jones Giannis S. Papaefstathiou Aaron M. Collins S. Parsons

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccqxc21

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CCDC 1952633: Experimental Crystal Structure Determination

The Cambridge Structural Database (2020)

Zahraa S. Al-Taie Simon R. Anetts Jeppe Christensen Simon J. Coles Peter N. Horton

10.5517/ccdc.csd.cc23jw5q

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CCDC 1952639: Experimental Crystal Structure Determination

The Cambridge Structural Database (2020)

Zahraa S. Al-Taie Simon R. Anetts Jeppe Christensen Simon J. Coles Peter N. Horton

10.5517/ccdc.csd.cc23jwcx

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CCDC 1952634: Experimental Crystal Structure Determination

The Cambridge Structural Database (2020)

Zahraa S. Al-Taie Simon R. Anetts Jeppe Christensen Simon J. Coles Peter N. Horton

10.5517/ccdc.csd.cc23jw6r

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CCDC 299513: Experimental Crystal Structure Determination

The Cambridge Structural Database (2006)

Leigh F. Jones P. Jensen B. Moubaraki K.J. Berry John F. Boas

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccb1nqq

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Elucidating cylindrospermopsin toxicity via synthetic analogues: An in vitro approach

Chemosphere (2019)

Daniel M. Evans Jack Hughes Leigh F. Jones P. J. Murphy Halina Falfushynska

Cylindrospermopsin

Uracil

Guanidine

Fragmentation

Hydroxyl radical

10.1016/j.chemosphere.2019.06.021

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Citations (18)

CCDC 1907531: Experimental Crystal Structure Determination

The Cambridge Structural Database (2019)

Mohammed B. Fugu Rebecca J. Ellaby Helen M. O’Connor Mateusz B. Pitak Wim Klooster

10.5517/ccdc.csd.cc220y8b

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CCDC 1894387: Experimental Crystal Structure Determination

The Cambridge Structural Database (2019)

Daniel M. Evans Jack Hughes Leigh F. Jones P. J. Murphy Halina Falfuskynska

10.5517/ccdc.csd.cc21l886

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CCDC 613021: Experimental Crystal Structure Determination

The Cambridge Structural Database (2006)

Leigh F. Jones K.D. Camm C.A. Kilner Malcolm A. Halcrow

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

10.5517/ccnkwwy

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Leigh F. Jones

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